Each step along our individual paths changes us. Some experiences grow body, mind, and soul. Other experiences cause those same parts of us to shrink and ache endlessly. The trick is to let each step teach you even if it pains you. When you dedicate yourself to a task with little hope of recognition or monetary gain, many steps on the path are painful. No matter how much you give or how many you touch, there are still more in need. We live in a harsh world. My hat/cancer bandana off to anyone on the path to healing themselves and/or helping a loved one get relief in the most natural way possible. It takes a lot of courage and resolve to reach the end of the modern medicine road and only be left with options you may be logically against (such as chemo). It’s just as difficult to dutifully stand by and genuinely unconditionally love someone whose body is in decline.
As difficult as those decisions are, being public about them makes those choices even harder, but the stories we tell and leave behind in this time when cannabis legality is in its infancy of revival are a testament to the plant, it healing and transformative powers, and the lives of those left searching for comfort when modern medicine can’t offer it. Each of us who has chosen to tell our tale in the public forum of our day (the internet, or public eye in general) is living history. My endless gratitude to all those out there playing nurse to a loved one so limited in physical ability. Watching the cannabis world work to change from prohibition to test markets for medical use to states defying the federal government to decriminalize for adult use has been a heart twisting journey every step of the road. Please don’t forget the chronically ill folks and their caregivers for each recreational bowl you enjoy or sell legally. We still have a long way to go to honor the people who put their entire lives and health on the line in order to create change. Let’s begin by more and more programs to help the low income patients among us.
After many years of dedication to the cause of cannabis education and healing, This is the greatest need I see in the movement today: Just too many folks with too little resources and too much pain while the price of cannabis remains a burden to their largely ssi/ssd funded existences while pounds of useable cannabis are grown in the name of someone suffering and sold elsewhere by their “caregiver” for a profit. We must do better by the low income legal cannabis patient if we ever hope to legalize cannabis for medicinal or recreational use across the board. But as an individual, I can only offer individual mercy. Lately I’ve been giving free oil to individuals legal in Colorado and to cannabis charities such as Greenfaith Ministries. We need to see more of this kind of mercy.
Feel free to wander around Kiefair.com, wish the site a happy anniversary, comment on and share your favorite articles from years past. Also feel free to comment on this post for any improvements or changes you would like to see to the site. Moving forward, I have a project to preserve samples of products I make and products available in the market for future research. I imagine a time when we are looking back at this period in our shared history as the dawn of cannabis legalization. I imagine scientists wanting to know exactly what we were using. To preserve this history, the best, the good, the bad, and the ugly, I have procured slides and lab vials to make samples to carry on after us.
My next article covers making your own massage oils. As a preview for those eagerly awaiting the write up on that article, Let us have a look at the history of extracting healing compounds or scent compounds from various plants. This history is essential to understanding the next article from kiefair.com
I invite you to come and visit the site through a sampling of the most read articles. Scroll below the photo for the top read articles according to my site’s stats, 2014 reading statistics. Let’s take a look at what people are reading.
The tale of one of many who has taken information they learned on kiefair.com and had the courage to use that knowledge to treat their own illnesses with it.
This post is not to debate with others about if J.R.R. Tolkien was a stoner or not. This post is for people who have already determined for themselves that he did like to suck on a weed pipe every now and again and who wonder about what is really in Lembas Bread.
Fat Freddy has had a sore on his back for about 3 years and it would not heal! We started putting Rick Simpson Oil on it on November 23, 2011 then the next day we checked it and then checked it every 3 days afterwards, changing the oil and bandage every 3 days as well! I documented the process as long as I was the live in maid/nurse for the patient. (WARNING THIS IS GRAPHIC!)
I do not look like I have a single drop of Mediterranean blood in me, so why do i care about this rare genetic disorder? Because the color of skin is only skin deep. Because despite the pale appearance of my exterior, I have the genetic ancestor from that part of the world who handed me this recessive trait. Because I have this disease and have to live with it…
A set of videos in Tribute to the writing of Hannah Hurnard, “Hind’s Feet on High Places” to Art of Breezy Kiefair i just put music and art to a book that has been a favorite since childhood… my mother used to read me that book…. call it a tribute to her and an introduction of the book to an audience that may otherwise remain unaware of it. I recommend it for anyone with anxiety or PTSD
Ronnie Lee Smith, aka Roland A Duby made much of Kiefair.com possible. In April 2014, he lost his battle with Leukemia after being falsely imprisoned by Yavapai county in Arizona. We got Ronnie out of jail, but only in time for him to die with a pipe in his hands. While Ronnie was alive, he tasked me to keep his oil making method alive. I have done my best to ensure I keep this task entrusted to me by making his method freely available to anyone willing to learn.
*****Note, I have not updated the review page in quite some time. Some of the dispensaries I have reviewed may no longer be in business. The quality at the locations I have reviewed may have changed due to a change in ownership, grower or extraction agreements. Nearly all of my reviews are of MEDICAL locations, so please check to see if they have a retail location before using any of these reviews for a vacation guide.
Do you use Kiefair.com? Do you support me giving out info on cannabis oil creation for free? Do you support my free oil program with the colorado cannabis charity known as Greenfaith Ministry? Well, you may be unaware that one little lady pays for all costs associated with KiefAir.com. The way the site stays afloat with its mini library of cannabis related reference information is through sales of art and books. Each year, I must make $300 in PROFITS from the art at my etsy store and my poetry book sales on amazon.com.
Have a look at some samples from my portfolio, all of these images may be purchased to support kiefair.com
Please remember I only make pennies per art print I sell, so I need to sell a lot of pieces each year. I was very worried about keeping the site open for 2015. The holiday season left me with not one sale. But People pulled together, and We are all set to keep the site open through February 2016!
This is the tale of how I kept the site open this time… previous years, the money had come from my medication budget. This year was different… this happened because a long time patron gifted me $100 to bring the hosting fee bar a little lower, but he was a special case, my first patron ever who seems to still want to pay more for some ceramic figures I did when I was about 14. He always sends me some cash during the winter holidays and on my birthday. In truth this anonymous donor has been more of a father to me than my own. One of the few positive male role models i have had in mu life. The rule is to spend it on something for myself. I misbehaved this year and give the gift to you. This year I’m put it towards continuing to give the gift of information via kiefair.com . Pebbles Trippet, a prominent writer for Skunk Magazine bought a clutch of 4×6 limited edition Maya Angelou memorial prints. Other patrons got posters or 8×10 prints and we made our goal to keep the site open! My thanks to all Patrons!
Each year, I allow you, the reader/viewer to decide if kiefair.com stays alive. If I get sales, all profit (save my usual tithe if 10% of all profits) will go to saving KiefAir.com. I hope we can do better on those sales and keep the site alive. Remember the power is yours to make it live or let the library die. Any image from my please bogart my art page is for sale except the maya portrait.
Portrait of Toni Fox by: Breezy Kiefiar Toni Commissioned me to turn one of her favorite digital images of herself into a canvas painting. Toni said she was so pleased with it that she has it displayed in her home office.
details: 1. Make your selection at the following link: https://www.facebook.com/kiefyart
2. Complete your transaction here and let the artist know what image you desire. Ms. Breezy will ship you a print in the size you desire right away!
If you buy a new print edition of this book (or purchased one in the past), you can buy the Kindle edition for only $0.99(Save 90%). Print edition purchase must be sold by Amazon.Learn more.
A poetry book centered on pot written by cannabis activist and artist under the influence, Breezy Kiefair. “Of Pain, poetry, and pot.” Is a collection of cannabis centered poetry in a neobeatnik style. It includes updated versions of Allen Allen Ginsberg – Howls “howl” and “america”, along with an update on “to whom it may concern” by Adrian Mitchell , a cannabis parody of Rifleman’s Creed and many other poems that are all my own.
This review is from: Of Pain, Poetry and Pot (Kindle Edition)
Would You Like To Pick Breezy’s Brain? This wonderful book is a chance to witness the creative process at work; author Breezy Kiefair (aka Breedheen O’Rilley) is the real deal, a gifted poet/journalist/activist on the forefront of the battle for medical marijuana patients’ rights and for truth in media. And speaking of truth, emotional truth is exactly what you’ll get here. Breezy isn’t afraid to take an open-eyed, unsparing look at society, at herself, at her illnesses, at the lies we tell ourselves and each other — and at the scintillating, breathtaking beauty which is more real and more powerful than all else. Highly recommended.
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This review is from: Of Pain, Poetry and Pot (Kindle Edition)
Written by someone very intimate with pain on many different levels. Beautiful and honest. I can’t wait to find out more about this amazing young woman. I originally borrowed this book. I have now read it twice and I have to own it. It must become a part of my permanent collection, along with anything else I can find which flows from this beautiful author.
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This review is from: Of Pain, Poetry and Pot (Kindle Edition)
The poems and rhythm that comes from the author’s feelings show you that she uses her medical cannabis passion and even frustrations to put her concerns into words we can understand. You can feel her pain – you can feel her pride. The transposed songs were a great touch.
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This multi-talented artist and writer amazed me with her insightful and sometimes heartbreaking poetry. Her artwork is not only beautiful, but different from any I have seen. I have actually ordered several individual prints off her website to give as gifts this Christmas. I highly recommend this book.
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This review is from: Of Pain, Poetry and Pot (Kindle Edition)
As an activist,a woman and a HUMAN BEING,, I could feel the pain in Ms. O’Rilley’s poetry. Yet I could also feel the triumph. A must for all “pot’ lovers, I got it for 2.99 for my Kindle and it was MORE than worth it. I’ve read these poems over and over, you will too.
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This review is from: Of Pain, Poetry and Pot (Kindle Edition)
This is an excellent book written by a very gifted, unique woman Breezy Keifair. I loved the whole book and have read it a couple of times so far. She is an artist that does her work under the influence of pot for the pain she is in and you can feel that pain with her words. I could really relate to that and a lot of other things in the book. I highly recommend this book. She is also a very gifted artist besides being a good poet and writer.
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Part 3 of the healing…..
Fat Freddy has had a sore on his back for about 3 years and it would not heal! We started putting Rick Simpson Oil on it on November 23, then the next day we checked it and then checked it every 3 days afterwards, changing the oil and bandage every 3 days as well! Here is the progress so far! (WARNING THIS IS GRAPHIC!)
For more info on “Fat
Freddy” of the Freak
Brother’s Comics (a
longtime cannabis freedom
fighter and the dude whose
back we are healing) please
visit: http://www.fatfreddy.com
I worked a private caregiver’s grow from July 2011 to November 2011. I was paid 1/4 oz medication, a roof over my head for the duration of the grow and use of years old trim with no “sugar” left to medicate me. I was supposed to be medicated for the duration of the grow, and recieve winter lodging NO MATTER WHAT for my efforts. Every silver lining has a touch of grey….
song choice: Grateful Dead, Touch of Grey (fair use, education)
Sour Diesel
Sativa 90 / Indica 10
Origins – Mexican Sativa x Chemo
Flowering – 75-80 days
Harvest – Early November
Beyond the citrus end of the pot palate spectrum lies a sour lemon tang tending toward the heay pungency of an open drum of diesel. This odor is so strong in Reservoir’s Sour Diesel strain that it may need to be masked during growing if stealth is a goal or necessity. Even when dried and carried in a pocket, these buds are smelly enough to raise suspicions. Reservoir drew on the Mexican sativa family and the sativa hybrid Chemo in an effort to produce the most psychedelic non-haze sativa possible.
Sour Diesel is a tall, thin plant suitable for sea or screen of green. She stretches in the first 3 weeks of flowering. By maturity she reaches a daunting 6 feet indoors in a slender version of the classic Christmas tree silhouette. Her foliage purples as it ages, and commonly displays pink-hued pistils. The buds are loose and spear-shaped.
Sour Diesel taste combined with its effects may be considered an “exptreme sport” version of cannabis. The stone pulls smokers into the sky fast with a viscerally uplifting pleasure and lots of consciousness expansion in the direction of spirituality. This good-vibe variety may help alleviate chronic depression, as well as the ordinary blahs by encouraging a change in perspective. http://www.kindgreenbuds.com/marijuana-strains/sourdiesel.html
Must be getting early, clocks are running late.
Paint by numbers morning sky, looks so phony.
Dawn is breaking everywhere, light a candle, curse the glare
Draw the curtains I don’t care ’cause it’s alright
I will get by, I will get by, I will get by, I will survive.I see you’ve got your list out, say your piece and get out.
Guess I get the gist of it ’cause it’s alright
Oh, well, anyway, sorry that you feel that way.
The only thing there is to say
Every silver lining’s got a touch of grey
I will get by, I will get by, I will get by, I will survive.It’s a lesson to me
The Ables and the beggars and the thieves
The ABC’s
We all think of
And try to keep a little graceIt’s a lesson to me
The Deltas and the East and the Freeze
The ABC’s we all think of
And try to give a little loveI know the rent is in arrears, the dog has not been fed in years
It’s even worse than it appears ’cause it’s alrightCow is given kerosene, kid can’t read at seventeen
The words he knows are all obscene ’cause it’s alright
I will get by, I will get by, I will get by, I will survive.It’s a lesson to me
The Deltas and the East and the Freeze
The ABC’s we all think of
And try to keep a little loveThe shoe is on the hand it fits, there’s all there really nothing much to it
Whistle through your teeth and spit ’cause it’s alrightOh, well, a touch of gray, kinda suits you anyway,
That’s all I had to say ’cause it’s alright
I will get by, I will get by, I will get by, I will survive.It’s a lesson to me,
The deltas and the East and the free
The ABC’s we all must face,
Try to save a little grace.We will get by. We will get by. We will get by. We will survive
We will get by. We will get by. We will get by. We will survive
#8 Most Viewed from my youtube channel
Hind’s Feet On High Places by Hannah Hurnard video 2
The introduction and first chapters of a set of videos in Tribute to the writing of Hannah Hurnard, “Hind’s Feet on High Places” to Art of Breezy Kiefair and the Music of Piotr Ilyich Tchaikovsky. Please give it 20 minutes of your time. Chapter 1 “Invitation to the High Places” i just put music and art to a book that has been a favorite since childhood… my mother used to read me that book…. call it a tribute to her and an introduction of the book to an audience that may otherwise remain unaware of it. I recommend it for anyone with anxiety or PTSD
info on the book from wikipedia:
Hinds’ Feet on High Places
From Wikipedia, the free encyclopedia
Hinds’ Feet on High Places
Author(s) Hannah Hurnard
Country United Kingdom
Language English
Genre(s) Christian
Publisher Christian Literature Crusade
Publication date 1955
Media type Print (Hardback & Paperback)
Pages 158 pp.
ISBN NA
Hinds’ Feet on High Places is an allegorical novel by English author Hannah Hurnard. Hinds’ Feet was written in 1955 and has become a very successful work of Christian fiction, seeing new editions published as recently as July, 2005.
[edit]Plot introduction
It is the story of a young woman named Much Afraid, and her journey away from her Fearing family and into the High Places of the Shepherd, guided by her two companions Sorrow and Suffering. It is an allegory of a Christian devotional life from salvation through maturity. It aims to show how a Christian is transformed from unbeliever to immature believer to mature believer, who walks daily with God as easily on the High Places of Joy in the spirit as in the daily life of mundane and oftentimes humiliating tasks that may cause Christians to lose perspective.
The book takes its title from Habakkuk 3:19, “The Lord God is my strength, and he will make my feet like hinds’ feet, and he will make me to walk upon mine high places.”
The story begins in the Valley of Humiliation with Much Afraid, being beset by the unwanted advances of her cousin, Craven Fear, who wishes to marry her. The Family of Fearings seems to have some strong similarities to the Addams Family. Much Afraid is ugly from all outward appearances, walking on club feet, sporting gnarled, deformed hands, and speaking from a crooked mouth that seems to have been made so by a stroke or the like.
The Good Shepherd is tender and gentle with Much Afraid, especially in the beginning. However, His many sudden departures may strike the reader as bizarre, given the human penchant to expect kindly souls to never do everything that may be interpreted as rude or as hurtful in any way. Yet, though the Shepherd leaves in a moment, He returns the same way at the first furtive cry of the forlorn little protagonist. “Come, Shepherd, for I am much afraid!”
When Much Afraid intimates that she would love to be able to dance upon the high places as do the surefooted deer, the Shepherd commends her for this desire. In order to accomplish this, he offers to “plant the seed of love” into her heart. At first sight of the long, black hawthorne-looking seed, she shrieks in fear. Soon, she relents, and after the initial intense pain, she senses that something is indeed different in her, though she still looks the same, for now.
Just when the reader thinks that Much Afraid is about to reach the High Places, the path turns downward towards a seemingly endless desert. There is an incident at the sheer cliff that must be climbed with only one rope, which hangs a long way down to her from the top. Then days are spent in a forest that is shrouded in a thick cloud of fog. During this time Much Afraid is sequestered with her two friends, Sorrow and Suffering, in a log cabin. The climax is an unexpected twist that comes as Much Afraid despairs of ever reaching the High Places.
[edit]Allusions/references to other works
The book bears some stylistic similarities to John Bunyan’s The Pilgrim’s Progress. The name of the protagonist, Much-Afraid, also appears first in Bunyan’s work.
[edit]References
#1 and # 2 Most Viewed from my youtube channel
Pink Floyd The Piper at the Gates of Dawn Side
video created by kiefair.com
music by pink floyd obviously
the audio has been reworked by Breezy Kiefair.The base audio was a live performance of “Tin Pan Alley” by Stevie Ray Vaughn and Double Trouble All images created by Breezy Kiefairl.
Dedicated to the low income cannabis patient left toking through tin pan Alley.
“Tin Pan Alley (aka Roughest Place in Town)” is track #23 on the album Essential Stevie Ray Vaughan. It was written by Geddins.
Tin Pan Alley (aka Roughest Place in Town)
Went down to Tin Pan Alley
See what was goin’ on
Things was too hot down there
Couldn’t stay very long
Hey, hey, hey, hey
Alley’s the roughest place I’ve ever been
All the peoples down there
Lord, they are livin’ for their whisky, wine and gin
She get up in the mornin’
Before the break a day
Before she can wash her face and hand
You know she really did go away
Hey, hey, hey, you tell
What kinda place can this here Alley be?
Well now, every women I get here
Every women I get to know
This Alley takes her away from me
I heard a pistol shoot
Yeah, and it was a .44
Somebody killed a crap shooter
‘Cause he didn’t shake, rattle and roll
Hey, hey, hey, hey
What kinda place can a Alley be?
All those people down there
Lord, they are livin’ for their whisky, wine and gin
I heard a woman scream
Yeah, and I peeked through the door
Some cat was workin’ on Annie with a
Lord, Lord with a two by four
Hey, hey, hey, hey
Alley’s the roughest place, I’ve ever been
All the people down there
Lord, they are killin’ for their whisky, wine and gin
I saw a cop standing there
With hand on his gun
Said this is a raid boy now
Run, run, nobody run
Hey, hey, hey, hey
Alley’s the roughest place, I’ve ever been
Yeah, they took me away from Alley
Lord, they took me right back to the pen
A bottle of Rubbing Alcohol (Photo credit: Wikipedia)
What solvent you use to create your cannabis oil is very important. If you are thinking of making your own oil, please take the time to educate yourself on the benefits and risks of any solvent you are thinking of using. When selecting your solvent, it is essential to be as educated as possible about the properties of that solvent.
I recommend use of food grade alcohol and nothing else for beginners (because the solvent is already food grade, it is good for beginners who are learning the method… that way, IF any solvent is left behind due to inexperience, it is still safe to consume.) Those proficient with use of alcohol as a solvent may then begin using isopropyl alcohol 91% (rubbing alcohol) once they have learned to tell when no alcohol remains. If you use a still, you can reclaim your solvent for reuse to cut down on costs. Another option is moonshine if you have a trusted source but note the word trusted. you want someone who has been making shine a long time with lots of living long term customers… if you get my drift
In this article, I am posting some links about Isopropyl alcohol and the compounds they add to make it bitter (not to make it toxic) . Now for how this applies to oil making…
below follows three articles with reference links on the properties of Iso alcohol
People commonly use rubbing alcohol as a disinfectant for minor cuts and scrapes. The two most common forms of rubbing alcohol are ethyl alcohol and isopropyl alcohol. Both types are extremely toxic in their concentrated forms. Because most alcoholic drinks contain ethanol, rubbing alcohol made from ethanol usually contains additives such as sucrose octaacetate and denatonium benzoate to prevent people from drinking the alcohol for pleasure. Isopropyl Alcohol Toxicity
Isopropyl alcohol, also called isopropanol, poses many risks to human beings. Inhaled fumes can cause respiratory tract irritation at low concentrations. At higher concentrations, the fumes can affect you like a narcotic, causing drowsiness, dizziness, loss of balance, headache, unconsciousness and even death. Ingestion of isopropanol can cause unconsciousness and death as well.
The approximate lethal dose of 90 to 100 percent isopropanol for human adults is only 250 millilters or about 8 ounces. While not fatal, ingesting smaller amounts can cause gastrointestinal problems, including cramps, pain, vomiting and diarrhea. Additionally, isopropanol vapors can irritate the eyes and splashes to the eyes can even burn your corneas.
Even though you may be accustomed to rubbing isopropyl alcohol on your skin, in excessive amounts it can cause irritation and redness. It is therefore important to use the rubbing alcohol only as directed by the instructions on the bottle.
Ethyl Alcohol Toxicity
Ethyl alcohol, also called ethanol, is toxic in many of the same ways as isopropyl alcohol. Ethanol causes severe irritation of the eyes accompanied by extreme sensitivity to light. If used excessively as rubbing alcohol, it can cause irritation and redness of the skin. It may even cause cyanosis, which is a condition characterized by a blue coloration of the skin, in your extremities.
Ingestion of ethanol causes nausea, diarrhea and vomiting. The system-wide toxicity that results from ethanol ingestion can cause acidosis of the blood and central nervous system depression characterized by excitement, followed by dizziness, drowsiness and nausea. This is the feeling of ‘drunkenness’ familiar to many people who drink alcoholic beverages.
Consumption of large quantities of ethanol leads eventually to collapse, coma and possibly death by respiratory failure. Chronic ingestion of ethanol causes fetal defects and liver damage. Lastly, inhalation of concentrated ethanol fumes also causes central nervous system effects. Respiratory irritation can be followed by nausea, dizziness, headache, unconsciousness and coma. Inhalation of extreme amounts of ethanol vapors can cause death by suffocation.
Additives
People commonly drink ethyl alcohol to become intoxicated. To prevent people from drinking ethanol-based rubbing alcohol, manufacturers add chemicals to make rubbing alcohol extremely bitter and undrinkable. These additives include sucrose octaacetate and denatonium benzoate. Neither chemical is toxic; indeed, small quantities of denatonium benzoate can be put on a child’s thumb to prevent her from sucking it.
IUPAC name[hide] Acetic acid [(2S,3S,4R,5R)-4-acetoxy-2,5-bis(acetoxymethyl)-2-[ [(2R,3R,4S,5R,6R)-3,4,5-triacetoxy-6- (acetoxymethyl)-2-tetrahydropyranyl]oxy]-3-tetrahydrofuranyl] ester
Identifiers CAS number 126-14-7 PubChem 31340
Jmol-3D images Image 1
SMILES
[show]
Properties
Molecular formula C28H38O19
Molar mass 678.59 g/mol
Appearance needles
Density 1.27 g/cm3 at 16°C
Melting point
86.5°C
Boiling point
250°C at 1 mmHg
Solubility in water slightly soluble in water
Solubility soluble in ethanol, diethyl ether, acetone, benzene, chloroform[1]
(verify) (what is: /?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references
Sucrose octaacetate is an acetylated derivative of sucrose. It is used commercially and industrially in a variety of applications. It is used as an inert ingredient in pesticides and herbicides. As of December 2005 sucrose octaacetate was determined by the EPA to be completely nonharmful as an ingredient in pesticides.[2]
Sucrose octaacetate has been approved by the FDA as a food additive. It has a bitter taste which has led to its use as bitterant and an aversive agent. The chemical has also been used to determine tasters from non-tasters in mice.[3].
reference: http://en.wikipedia.org/wiki/Sucrose_octaacetate
Denatonium benzoate is one of the most bitter substances known. Just a few parts per million will make a product so bitter that children and pets will not be able to swallow it. Denatonium benzoate makes sweet but highly toxic products such as antifreeze and detergents taste foul. Research shows that people can detect denatonium benzoate in water at 50 parts per billion. Denatonium benzoate is bitter at 1 to 10 ppm and most products will become undrinkable at 30 to 100 ppm. Denatonium benzoate is also stable and inert. In addition, so little is needed that the properties of the product remain unchanged.
Both the National Safety Council and the American Medical Association recommend adding denatonium benzoate to products that are defined as mild to moderately toxic. Some countries, such as France, have made denatonium benzoate mandatory in antifreeze. Others such as Italy have made denatonium benzoate the number one denaturant for ethanol. The State of Oregon has required that it be added to antifreeze and windshield wiper fluid since 1995. We offer denatonium benzoate in powder form, both technical and pharmaceutical grade, and in a granular form (technical grade only). Your best source for denatonium benzoate is Aversion Technologies, the world’s only company dedicated to the supply of products to protect people, plants and pets.
reference: http://www.denatonium-benzoate.com/
A friend of mine was donated some phoenix tears oil from an understandably unnamed source. She could not take it to a lab for testing and was afraid to use it. She put a sample into my hands. So, on Monday I tested it. I have a high tolerance and was in a lot of pain, so I took a larger than a grain of rice dab. From the moment it touched my tongue, it burned. It was naphtha! I knew it, but it was far too late. Soon, My nervous system was soon on fire. Then the crazy symptoms came. I got to a point of pain and insanity that was torture for myself and all around me. The crazy lasted for days… the pain is still there. If you have mental health issues on any level, avoid naphtha extracted products like the plague! Its not worth it. It causes cancer too.
naphtha is so toxic, the Department of Defense (DoD) uses is as a template for how they classify “dangerous” chemicals…. you’re using naphtha to make your Rick Simpson – Phoenix Tears therapy? your’re inviting so much attention from the government it is stupid. They track each and every purchase of that substance btw.
Material Safety Data Sheet
Naphtha
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : Naphtha
Synonyms : Light Naphtha, Japan Open Spec Bonded Naphtha, SNG Naphtha, Light Cat
Naphtha, Sweet Virgin Naphtha (SVN), Debutanized Naphtha, Atmospheric
Naphtha (DAN), HCU Light Naphtha, Light CR Gasoline, Full Range Cracked
Naphtha, Full Range Hydrocracked Naphtha, Full Range Reformed Naphtha,
Light Chemical Treated Naphtha, Light Cracked Naphtha, Light Hydrocracked
Naphtha, Light Hydrotreated Naphtha, Aviation Alkylate Naphtha, 888100004450
MSDS Number : 888100004450 Version : 2.12
Product Use Description : Fuel Component, Refinery Intermediate Stream
Company : For: Tesoro Refining & Marketing Co.
19100 Ridgewood Parkway, San Antonio, TX 78259
Tesoro Call Center : (877) 783-7676 Chemtrec
(Emergency Contact)
: (800) 424-9300
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Regulatory status : This material is considered hazardous by the Occupational Safety and Health
Administration (OSHA) Hazard Communication Standard (29 CFR 1910.1200).
Signal Word : DANGER
Hazard Summary : Extremely flammable. Irritating to eyes and respiratory system. Affects central
nervous system. Harmful or fatal if swallowed. Aspiration Hazard.
Potential Health Effects
Eyes : High vapor concentration or contact may cause irritation and discomfort.
Skin : Brief contact may cause slight irritation. Skin irritation leading to dermatitis may
occur upon prolonged or repeated contact. Can be absorbed through skin.
Ingestion : Aspiration hazard if liquid is inhaled into lungs, particularly from vomiting after
ingestion. Aspiration may result in chemical pneumonia, severe lung damage,
respiratory failure and even death.
Inhalation : Vapors or mists from this material can irritate the nose, throat, and lungs, and
can cause signs and symptoms of central nervous system depression,
depending on the concentration and duration of exposure. Inhalation of high
concentrations may cause central nervous system depression such as dizziness,
Specific Hazard
Reactivity
Health
NFPA: Flammability
1 0
3
FLAMMABILITY
PHYSICAL
HEALTH
3
0
1
HMIS III:
0 = Insignificant, 1 = Slight, 2 = Moderate,
3 = High, 4 = ExtremeMATERIAL SAFETY DATA SHEET NAPHTHA Page 2 of 14
2 / 14
drowsiness, headache, and similar narcotic symptoms, but no long-term effects.
Chronic Exposure : Long-term exposure may cause effects to specific organs, such as to the liver,
kidneys, blood, nervous system, and skin. Contains benzene, which can cause
blood disease, including anemia and leukemia.
Target Organs : Skin, Central nervous system, Liver, Kidney, Blood
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS-No. Weight %
Naphtha; Low boiling point naphtha 8030-30-6 100%
N-hexane 110-54-3 25 – 35%
Xylene 1330-20-7 25 – 35%
Toluene 108-88-3 15 – 20%
Cyclohexane 110-82-7 15 – 20%
Pentane 109-66-0 15 – 20%
Heptane [and isomers] 142-82-5 12.5 – 15%
Ethylbenzene 100-41-4 5 – 7%
Benzene 71-43-2 3 – 5% 1,2,4-Trimethylbenzene 95-63-6 2 – 3%
Sulfur 7704-34-9 0 – 1.5%
SECTION 4. FIRST AID MEASURES
General advice : Remove from exposure, lie down. In the case of accident or if you feel unwell,
seek medical advice immediately (show the label where possible). When
symptoms persist or in all cases of doubt, seek medical advice. Never give
anything by mouth to an unconscious person. Take off all contaminated clothing
immediately and thoroughly wash material from skin.
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Seek medical attention immediately.
Skin contact : In case of contact, immediately flush skin with plenty of water. Take off
contaminated clothing and shoes immediately. Wash contaminated clothing
before re-use. Contaminated leather, particularly footwear, must be discarded.
Note that contaminated clothing may be a fire hazard. Seek medical advice if
symptoms persist or develop.
Eye contact : Remove contact lenses. In the case of contact with eyes, rinse immediately with
plenty of water and seek medical advice.
Ingestion : If swallowed Do NOT induce vomiting. Never give anything by mouth to an
unconscious person. Seek medical attention immediately. MATERIAL SAFETY DATA SHEET NAPHTHA Page 3 of 14
3 / 14
Notes to physician : Symptoms: Dizziness, Discomfort, Headache, Nausea, Kidney disorders, Liver
disorders.
SECTION 5. FIRE-FIGHTING MEASURES
Form : Liquid
Flash point -typical : -21.7 °C (-7.1 °F)
Auto Ignition temperature : 225 °C (437 °F)
Lower explosive limit : 1.2 %(V)
Upper explosive limit : 6.9 % (V)
Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Do not
use a solid water stream as it may scatter and spread fire.
Specific hazards during fire
fighting
: SMALL FIRES: Any extinguisher suitable for Class B fires, dry chemical, CO2,
water spray, fire fighting foam, or Halon.
LARGE FIRES: Water spray, fog or fire fighting foam. Water may be ineffective for
fighting the fire, but may be used to cool fire-exposed containers.
Special protective equipment
for fire-fighters
: Fire fighters should wear positive pressure self-contained breathing apparatus
(SCBA) and full turnout gear. Firefighters’ protective clothing will provide limited
protection.
Further information : Isolate area around container involved in fire. Cool tanks, shells, and containers
exposed to fire and excessive heat with water. For massive fires the use of
unmanned hose holders or monitor nozzles may be advantageous to further
minimize personnel exposure. Major fires may require withdrawal, allowing the
tank to burn. Large storage tank fires typically require specially trained personnel
and equipment to extinguish the fire, often including the need for properly applied
fire fighting foam. Exposure to decomposition products may be a hazard to health.
Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment. Use water spray to cool unopened containers. Fire
residues and contaminated fire extinguishing water must be disposed of in
accordance with local regulations.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Evacuate personnel to safe areas. Ventilate the area. Remove all sources of
ignition. Response and clean-up crews must be properly trained and must utilize
proper protective equipment (see Section 8).
Environmental precautions : Should not be released into the environment. Avoid subsoil penetration. If the
product contaminates rivers and lakes or drains, inform respective authorities.
Methods for cleaning up : Contain and collect spillage with non-combustible absorbent material, (e.g. sand,
earth, diatomaceous earth, vermiculite) and place in container for disposal
according to local / national regulations.
SECTION 7. HANDLING AND STORAGE
Handling : Keep away from fire, sparks and heated surfaces. No smoking near areas where
material is stored or handled. The product should only be stored and handled in MATERIAL SAFETY DATA SHEET NAPHTHA Page 4 of 14
4 / 14
areas with intrinsically safe electrical classification.
Advice on protection against
fire and explosion
: Hydrocarbon liquids including this product can act as a non-conductive flammable
liquid (or static accumulators), and may form ignitable vapor-air mixtures in storage
tanks or other containers. Precautions to prevent static-initated fire or explosion
during transfer, storage or handling, include but are not limited to these examples:
(1) Ground and bond containers during product transfers. Grounding and
bonding may not be adequate protection to prevent ignition or explosion of
hydrocarbon liquids and vapors that are static accumulators.
(2) Special slow load procedures for “switch loading” must be followed to
avoid the static ignition hazard that can exist when higher flash point
material (such as fuel oil or diesel) is loaded into tanks previously
containing low flash point products (such gasoline or naphtha).
(3) Storage tank level floats must be effectively bonded.
For more information on precautions to prevent static-initated fire or explosion, see
NFPA 77, Recommended Practice on Static Electricity (2007), and API
Recommended Practice 2003, Protection Against Ignitions Arising Out of Static,
Lightning, and Stray Currents (2008).
Dust explosion class : Not applicable
Requirements for storage
areas and containers
: Keep away from flame, sparks, excessive temperatures and open flame. Use
approved containers. Keep containers closed and clearly labeled. Empty or
partially full product containers or vessels may contain explosive vapors. Do not
pressurize, cut, heat, weld or expose containers to sources of ignition. Store in a
well-ventilated area. The storage area should comply with NFPA 30 “Flammable
and Combustible Liquid Code”. The cleaning of tanks previously containing this
product should follow API Recommended Practice (RP) 2013 “Cleaning Mobile
Tanks In Flammable and Combustible Liquid Service” and API RP 2015 “Cleaning
Petroleum Storage Tanks”.
Advice on common storage : Keep away from food, drink and animal feed. Incompatible with oxidizing agents.
Incompatible with acids.
Other data : No decomposition if stored and applied as directed.
SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
List Components CAS-No. Type: Value
OSHA Benzene – 29 CFR 1910.1028 71-43-2 TWA 1 ppm
71-43-2 STEL 5 ppm
71-43-2 OSHA_AL 0.5 ppm
OSHA Z1 Naphtha; Low boiling point naphtha 8030-30-6 PEL 100 ppm 400 mg/m3
Xylene 1330-20-7 PEL 100 ppm 435 mg/m3
N-hexane 110-54-3 PEL 500 ppm 1,800 mg/m3
Cyclohexane 110-82-7 PEL 300 ppm 1,050 mg/m3
Heptane [and isomers] 142-82-5 PEL 500 ppm 2,000 mg/m3
Ethylbenzene 100-41-4 PEL 100 ppm 435 mg/m3
ACGIH Naphtha; Low boiling point naphtha 8030-30-6 TWA 400 ppm MATERIAL SAFETY DATA SHEET NAPHTHA Page 5 of 14
5 / 14
Xylene 1330-20-7 TWA 100 ppm
1330-20-7 STEL 150 ppm
N-hexane 110-54-3 TWA 50 ppm
Toluene 108-88-3 TWA 50 ppm
Cyclohexane 110-82-7 TWA 100 ppm
Pentane 109-66-0 TWA 600 ppm
Heptane [and isomers] 142-82-5 TWA 400 ppm
142-82-5 STEL 500 ppm
Ethylbenzene 100-41-4 TWA 100 ppm
100-41-4 STEL 125 ppm
Benzene 71-43-2 TWA 0.5 ppm
71-43-2 STEL 2.5 ppm
Engineering measures : Use adequate ventilation to keep gas and vapor concentrations of this product
below occupational exposure and flammability limits, particularly in confined
spaces. Use only intrinsically safe electrical equipment approved for use in
classified areas.
Eye protection : Safety glasses or goggles are recommended where there is a possibility of
splashing or spraying. Ensure that eyewash stations and safety showers are close
to the workstation location.
Hand protection : Gloves constructed of nitrile or neoprene are recommended. Consult manufacturer
specifications for further information.
Skin and body protection : If needed to prevent skin contact, chemical protective clothing such as of DuPont
TyChem®, Saranex or equivalent recommended based on degree of exposure.
The resistance of specific material may vary from product to product as well as
with degree of exposure.
Respiratory protection : A NIOSH/ MSHA-approved air-purifying respirator with organic vapor cartridges or
canister may be permissible under certain circumstances where airborne
concentrations are or may be expected to exceed exposure limits or for odor or
irritation. Protection provided by air-purifying respirators is limited. Refer to OSHA
29 CFR 1910.134, ANSI Z88.2-1992, NIOSH Respirator Decision Logic, and the
manufacturer for additional guidance on respiratory protection selection. Use a
NIOSH/ MSHA-approved positive-pressure supplied-air respirator if there is a
potential for uncontrolled release, exposure levels are not known, in oxygendeficient atmospheres, or any other circumstance where an air-purifying respirator
may not provide adequate protection.
Work / Hygiene practices : Emergency eye wash capability should be available in the near proximity to
operations presenting a potential splash exposure. Use good personal hygiene
practices. Avoid repeated and/or prolonged skin exposure. Wash hands before
eating, drinking, smoking, or using toilet facilities. Do not use as a cleaning solvent
on the skin. Do not use solvents or harsh abrasive skin cleaners for washing this
product from exposed skin areas. Waterless hand cleaners are effective.
Promptly remove contaminated clothing and launder before reuse. Use care when
laundering to prevent the formation of flammable vapors which could ignite via
washer or dryer. Consider the need to discard contaminated leather shoes and
gloves. MATERIAL SAFETY DATA SHEET NAPHTHA Page 6 of 14
6 / 14
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid
Appearance : Colorless to light yellow
Odor : Characteristic hydrocarbon-like
Flash point – typical : -21.7 °C (-7.1 °F)
Auto Ignition temperature : 225 °C (437 °F)
Thermal decomposition : Heating can release hazardous gases, No decomposition if stored and applied as
directed.
Lower explosive limit : 1.2 % (V)
Upper explosive limit : 6.9 % (V)
pH : Not applicable
Specific gravity : 0.77 (H20=1)
Boiling point : 26.7 – 148.9 °C(80.1 – 300.0 °F)
Vapor Pressure : 758 – 896 hPa
at 20 °C (68 °F)
Vapor Density (Air = 1) : 3.5
Water solubility : Negligible
Viscosity, kinematic : Not determined
Percent Volatiles : 100 %
Work / Hygiene practices Emergency eye wash capability should be available in the near proximity to
operations presenting a potential splash exposure. Use good personal hygiene
practices. Avoid repeated and/or prolonged skin exposure. Wash hands before
eating, drinking, smoking, or using toilet facilities. Do not use as a cleaning
solvent on the skin. Do not use solvents or harsh abrasive skin cleaners for
washing this product from exposed skin areas. Waterless hand cleaners are
effective. Promptly remove contaminated clothing and launder before reuse. Use
care when laundering to prevent the formation of flammable vapors which could
ignite via washer or dryer. Consider the need to discard contaminated leather
shoes and gloves.
SECTION 10. STABILITY AND REACTIVITY
Conditions to avoid : Avoid high temperatures, open flames, sparks, welding, smoking and other
ignition sources.
Materials to avoid : Strong acids and strong bases. Oxidizing agents.
Hazardous decomposition
products
: Carbon monoxide, carbon dioxide and noncombusted hydrocarbons (smoke).
Thermal decomposition : Heating can release hazardous gases. No decomposition if stored and applied as
directed.
Hazardous reactions : Vapors may form explosive mixture with air. Hazardous polymerization does not
occur. Note: Stable under recommended storage conditions. MATERIAL SAFETY DATA SHEET NAPHTHA Page 7 of 14
7 / 14
SECTION 11. TOXICOLOGICAL INFORMATION
Carcinogenicity
NTP : Benzene (CAS-No.: 71-43-2)
IARC : Ethylbenzene (CAS-No.: 100-41-4)
Benzene (CAS-No.: 71-43-2)
OSHA : Benzene (CAS-No.: 71-43-2)
CA Prop 65 : WARNING! This product contains a chemical known to the State of California to
cause cancer.
Ethylbenzene (CAS-No.: 100-41-4)
Benzene (CAS-No.: 71-43-2)
: WARNING! This product contains a chemical known to the State of California to
cause birth defects or other reproductive harm.
Toluene (CAS-No.: 108-88-3)
Benzene (CAS-No.: 71-43-2)
Skin irritation : Repeated or prolonged contact with the preparation may cause removal of natural
fat from the skin resulting in desiccation of the skin.
The product may be absorbed through the skin.
Eye irritation : The liquid splashed in the eyes may cause irritation and reversible damage.
Strong lachrymation can make it difficult to escape
Further information : This product contains benzene. Human health studies indicate that prolonged
and/or repeated overexposure to benzene may cause damage to the blood-forming
system (particularly bone marrow), and serious blood disorders such as aplastic
anemia and leukemia. Benzene is listed as a human carcinogen by the NTP, IARC,
OSHA and ACGIH. Acute toxicity of benzene results primarily from depression of
the central nervous system (CNS). Inhalation of concentrations over 50 ppm can
produce headache, lassitude, weariness, dizziness, drowsiness, or excitation.
Exposure to very high levels can result in unconsciousness and death.
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and
vomiting.
Ingestion may cause gastrointestinal disturbances, including irritation, nausea,
vomiting and diarrhea, and central nervous (brain) effects similar to alcohol
intoxication. In severe cases, tremors, convulsions, loss of consciousness, coma,
respiratory arrest and death may occur.
Component:MATERIAL SAFETY DATA SHEET NAPHTHA Page 8 of 14
8 / 14
N-hexane 110-54-3 Acute oral toxicity: LD50 rat
Dose: 25,000 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: 2,001 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 171.6 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Skin irritation
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
Teratogenicity: N11.00418960
Xylene 1330-20-7 Acute oral toxicity: LD50 rat
Dose: 2,840 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: ca. 4,500 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 6,350 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Mild skin irritation
Repeated or prolonged exposure may cause skin irritation and dermatitis, due to
degreasing properties of the product.
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
Toluene 108-88-3 Acute oral toxicity: LD50 rat
Dose: 636 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: 12,124 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 49 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Mild skin irritation
Prolonged skin contact may defat the skin and produce dermatitis.
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
Cyclohexane 110-82-7 Acute dermal toxicity: LD50 rabbit
Dose: 2,001 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 14 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Skin irritation
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
Pentane 109-66-0 Acute oral toxicity: LD50 rat
Dose: 2,001 mg/kg
Acute inhalation toxicity: LC50 rat MATERIAL SAFETY DATA SHEET NAPHTHA Page 9 of 14
9 / 14
Dose: 364 mg/l
Exposure time: 4 h
Skin irritation: Repeated or prolonged exposure may cause skin irritation and dermatitis,
due to degreasing properties of the product.
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
Heptane [and isomers] 142-82-5 Acute oral toxicity: LD50 rat
Dose: 15,001 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 103 g/m3
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Skin irritation
Repeated or prolonged exposure may cause skin irritation and dermatitis, due to
degreasing properties of the product.
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
Ethylbenzene 100-41-4 Acute oral toxicity: LD50 rat
Dose: 3,500 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: 15,500 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 18 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Mild skin irritation
Eye irritation: Classification: Irritating to eyes.
Result: Risk of serious damage to eyes.
Benzene 71-43-2 Acute oral toxicity: LD50 rat
Dose: 930 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 44 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Mild skin irritation
Repeated or prolonged exposure may cause skin irritation and dermatitis, due to
degreasing properties of the product.
Eye irritation: Classification: Irritating to eyes.
Result: Risk of serious damage to eyes.
1,2,4-Trimethylbenzene 95-63-6 Acute inhalation toxicity: LC50 rat
Dose: 18 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Skin irritation
Eye irritation: Classification: Irritating to eyes.
Result: Eye irritationMATERIAL SAFETY DATA SHEET NAPHTHA Page 10 of 14
10 / 14
Sulfur 7704-34-9 Acute oral toxicity: LD50 rat
Dose: 5,001 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: 2,001 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 9.24 mg/l
Exposure time: 4 h
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
SECTION 12. ECOLOGICAL INFORMATION
Additional ecological
information
: Keep out of sewers, drainage areas, and waterways. Report spills and releases, as
applicable, under Federal and State regulations.
Component:
N-hexane 110-54-3 Toxicity to fish:
LC50
Species: Pimephales promelas (fathead minnow)
Dose: 2.5 mg/l
Exposure time: 96 h
Acute and prolonged toxicity for aquatic invertebrates:
EC50
Species: Daphnia magna (Water flea)
Dose: 2.1 mg/l
Exposure time: 48 h
Toluene 108-88-3 Toxicity to fish:
LC50
Species: Carassius auratus (goldfish)
Dose: 13 mg/l
Exposure time: 96 h
Acute and prolonged toxicity for aquatic invertebrates:
EC50
Species: Daphnia magna (Water flea)
Dose: 11.5 mg/l
Exposure time: 48 h
Toxicity to algae:
IC50
Species: Selenastrum capricornutum (green algae)
Dose: 12 mg/l
Exposure time: 72 h
Cyclohexane 110-82-7 Acute and prolonged toxicity for aquatic invertebrates:
EC50
Species: Daphnia magna (Water flea)
Dose: 3.78 mg/l
Exposure time: 48 h
Pentane 109-66-0 Acute and prolonged toxicity for aquatic invertebrates:
EC50
Species: Daphnia magna (Water flea)
Dose: 9.74 mg/l
Exposure time: 48 h
Heptane [and isomers] 142-82-5 Toxicity to fish:
LC50
Species: Carassius auratus (goldfish)
Dose: 4 mg/l
Exposure time: 24 h MATERIAL SAFETY DATA SHEET NAPHTHA Page 11 of 14
11 / 14
Acute and prolonged toxicity for aquatic invertebrates:
EC50
Species: Daphnia magna (Water flea)
Dose: 1.5 mg/l
Exposure time: 48 h
1,2,4-Trimethylbenzene 95-63-6 Toxicity to fish:
LC50
Species: Pimephales promelas (fathead minnow)
Dose: 7.72 mg/l
Exposure time: 96 h
Acute and prolonged toxicity for aquatic invertebrates:
EC50
Species: Daphnia
Dose: 3.6 mg/l
Exposure time: 48 h
Sulfur 7704-34-9 Acute and prolonged toxicity for aquatic invertebrates:
EC0
Species: Daphnia magna (Water flea)
Dose: > 10,000 mg/l
Exposure time: 24 h
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal : Dispose of container and unused contents in accordance with federal, state and
local requirements.
SECTION 14. TRANSPORT INFORMATION
CFR
Proper shipping name : PETROLEUM DISTILLATES, N.O.S.
UN-No. : 1268
Class : 3
Packing group : II
Hazard inducer : (Naphtha; Low boiling point naphtha)
TDG
Proper shipping name : PETROLEUM DISTILLATES, N.O.S.
UN-No. : UN1268
Class : 3
Packing group : II
Hazard inducer : (Naphtha; Low boiling point naphtha)
IATA Cargo Transport
UN UN-No. : UN1268
Description of the goods : PETROLEUM DISTILLATES, N.O.S.
(Naphtha; Low boiling point naphtha)
Class : 3
Packaging group : II
ICAO-Labels : 3
Packing instruction (cargo
aircraft)
: 364
Packing instruction (cargo
aircraft)
: Y341 MATERIAL SAFETY DATA SHEET NAPHTHA Page 12 of 14
12 / 14
IATA Passenger Transport
UN UN-No. : UN1268
Description of the goods : PETROLEUM DISTILLATES, N.O.S.
(Naphtha; Low boiling point naphtha)
Class : 3
Packaging group : II
ICAO-Labels : 3
Packing instruction
(passenger aircraft)
: 353
Packing instruction
(passenger aircraft)
: Y341
IMDG-Code
UN-No. : UN 1268
Description of the goods : PETROLEUM DISTILLATES, N.O.S.
(Naphtha; Low boiling point naphtha)
Class : 3
Packaging group : II
IMDG-Labels : 3
EmS Number : F-E S-E
Marine pollutant : No
SECTION 15. REGULATORY INFORMATION
OSHA Hazards : Flammable liquid
Moderate skin irritant
Severe eye irritant
Carcinogen
Teratogen
TSCA Status : On TSCA Inventory
DSL Status : All components of this product are on the Canadian DSL list.
SARA 311/312 Hazards : Fire Hazard
Acute Health Hazard
Chronic Health Hazard
SARA III US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 313 Toxic
Chemicals (40 CFR 372.65) – Supplier Notification Required
Components CAS-No.
1,2,4-Trimethylbenzene 95-63-6
Benzene 71-43-2
Ethylbenzene 100-41-4
Cyclohexane 110-82-7
Toluene 108-88-3
N-hexane 110-54-3
Xylene 1330-20-7
PENN RTK US. Pennsylvania Worker and Community Right-to-Know Law (34 Pa. Code Chap. 301-323) MATERIAL SAFETY DATA SHEET NAPHTHA Page 13 of 14
13 / 14
Components CAS-No.
Heptane [and isomers] 142-82-5
Ethylbenzene 100-41-4
Benzene 71-43-2
1,2,4-Trimethylbenzene 95-63-6
Sulfur 7704-34-9
Pentane 109-66-0
Naphtha; Low boiling point naphtha 8030-30-6
Xylene 1330-20-7
N-hexane 110-54-3
Toluene 108-88-3
Cyclohexane 110-82-7
MASS RTK US. Massachusetts Commonwealth’s Right-to-Know Law (Appendix A to 105 Code of Massachusetts Regulations
Section 670.000)
Components CAS-No.
Heptane [and isomers] 142-82-5
Ethylbenzene 100-41-4
Benzene 71-43-2
1,2,4-Trimethylbenzene 95-63-6
Sulfur 7704-34-9
Naphtha; Low boiling point naphtha 8030-30-6
Xylene 1330-20-7
N-hexane 110-54-3
Toluene 108-88-3
Cyclohexane 110-82-7
NJ RTK US. New Jersey Worker and Community Right-to-Know Act (New Jersey Statute Annotated Section 34:5A-5)
Components CAS-No.
Heptane [and isomers] 142-82-5
Ethylbenzene 100-41-4
Benzene 71-43-2
1,2,4-Trimethylbenzene 95-63-6
Sulfur 7704-34-9
Naphtha; Low boiling point naphtha 8030-30-6
Xylene 1330-20-7
N-hexane 110-54-3 MATERIAL SAFETY DATA SHEET NAPHTHA Page 14 of 14
14 / 14
Toluene 108-88-3
Cyclohexane 110-82-7
CERCLA SECTION 103 and SARA SECTION 304 (RELEASE
TO THE ENVIROMENT)
The CERCLA definition of hazardous substances contains a
“petroleum exclusion” clause which exempts crude oil. Fractions of
crude oil, and products (both finished and intermediate) from the
crude oil refining process and any indigenous components of such
from the CERCLA Section 103 reporting requirements. However,
other federal reporting requirements, including SARA Section 304,
as well as the Clean Water Act may still apply.
California Prop. 65 : WARNING! This product contains a chemical known to the State of California to
cause cancer.
Ethylbenzene 100-41-4
Benzene 71-43-2
WARNING! This product contains a chemical known to the State of California to
cause birth defects or other reproductive harm.
Toluene 108-88-3
Benzene 71-43-2
SECTION 16. OTHER INFORMATION
Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text.
Template
Prepared by
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Revision Date : 01/27/2011
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DEPARTMENT OF DEFENSE
HAZARDOUS CHEMICAL
WARNING LABELING SYSTEM
OFFICE OF THE
ASSISTANT SECRETARY OF DEFENSE
(FORCE MANAGEMENT AND PERSONNEL)
JUNE 1989.
.
June 1989
Department of Defense Hazardous Chemical Warning
Labeling System
.
FOREWORD
,.,
This Handbook is issued under the authority of, and in accordance with, DoD Instruction 6050.5, ‘Hazardous Material Information System, ” January 25, 1978. This Handbook, the “Department of Defense Hazardous Chemical Warning Labeling System, establishes a standard label format and uniform labeling system throughout DoD for identifying hazardous materials used by DoD personnel.
In addition, this publication provides an additional training resource to help DoD comply with the training and worker information requirements of the Occupational Safety and Health Administration’ s Hazard Communication Standard (29 C. F. Il. 1910.1200) .
This publication applies to the Office of the Secretary of Defense, the Military Departments, the Joint Staff, the unified
and Specified Commandsr and the Defense Agencies. It is effective immediately.
Forward recommended changes to this Handbook through appropriate
channels to:
Director, Safety and Occupational Health Policy
OASD (FM&P), ODASD (FSE&S)
RCIOITI 3A272, The Pentagon Washington, D.C. 20301-4000
DoD Components may obtain copies of this Handbook through their
own publications channels. Other Federal Agencies and the public
may obtain copies from the U.S. Department of Commerce, National
4 Technical Information Service, 5285 Port Royal Road, Springfield,
Excerpt from GUIDE 128 [Flammable Liquids (Non-Polar / Water-Immiscible)]:HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. Substance may be transported hot. If molten aluminum is involved, refer to GUIDE 169. (ERG, 2008)
Inhalation of concentrated vapor may cause intoxication. Liquid is not very irritating to skin or eyes but may get into lungs by aspiration. (USCG, 1999)
Reactivity Profile
PETROLEUM NAPHTHA, [FLAMMABLE LIQUID LABEL] may be incompatible with strong oxidizing agents like nitric acid. Charring may occur followed by ignition of unreacted material and other nearby combustibles. In other settings, mostly unreactive. Not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents. When heated sufficiently or when ignited in the presence of air, oxygen or strong oxidizing agents, burns exothermically to produce mostly carbon dioxide and water.
Fire Extinguishing Agents Not to Be Used: Water may be ineffective.Fire Extinguishing Agents: Foam, carbon dioxide, or dry chemical (USCG, 1999)
Non-Fire Response
Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. (AAR, 2003)
Skin: Wear appropriate personal protective clothing to prevent skin contact.Eyes: Wear appropriate eye protection to prevent eye contact.Wash skin: The worker should immediately wash the skin when it becomes contaminated.Remove: Work clothing that becomes wet or significantly contaminated should be removed and replaced.Change: No recommendation is made specifying the need for the worker to change clothing after the work shift. (NIOSH, 2003)
Eye: If this chemical contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately. Contact lenses should not be worn when working with this chemical.Skin: If this chemical contacts the skin, promptly wash the contaminated skin with soap and water. If this chemical penetrates the clothing promptly remove the clothing and wash the skin with soap and water. Get medical attention promptly.Breathing: If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. If breathing has stopped, perform mouth-to-mouth resuscitation. Keep the affected person warm and at rest. Get medical attention as soon as possible.Swallow: If this chemical has been swallowed, get medical attention immediately. (NIOSH, 1997)
did you know that naptha is the key component in pavement sealer?
read all about it from the Federal Aviation Administration. now why would you put this stuff in your medicine?
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