A friend of mine was donated some phoenix tears oil from an understandably unnamed source. She could not take it to a lab for testing and was afraid to use it. She put a sample into my hands. So, on Monday I tested it. I have a high tolerance and was in a lot of pain, so I took a larger than a grain of rice dab. From the moment it touched my tongue, it burned. It was naphtha! I knew it, but it was far too late. Soon, My nervous system was soon on fire. Then the crazy symptoms came. I got to a point of pain and insanity that was torture for myself and all around me. The crazy lasted for days… the pain is still there. If you have mental health issues on any level, avoid naphtha extracted products like the plague! Its not worth it. It causes cancer too.
naphtha is so toxic, the Department of Defense (DoD) uses is as a template for how they classify “dangerous” chemicals…. you’re using naphtha to make your Rick Simpson – Phoenix Tears therapy? your’re inviting so much attention from the government it is stupid. They track each and every purchase of that substance btw.
Material Safety Data Sheet
Naphtha
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : Naphtha
Synonyms : Light Naphtha, Japan Open Spec Bonded Naphtha, SNG Naphtha, Light Cat
Naphtha, Sweet Virgin Naphtha (SVN), Debutanized Naphtha, Atmospheric
Naphtha (DAN), HCU Light Naphtha, Light CR Gasoline, Full Range Cracked
Naphtha, Full Range Hydrocracked Naphtha, Full Range Reformed Naphtha,
Light Chemical Treated Naphtha, Light Cracked Naphtha, Light Hydrocracked
Naphtha, Light Hydrotreated Naphtha, Aviation Alkylate Naphtha, 888100004450
MSDS Number : 888100004450 Version : 2.12
Product Use Description : Fuel Component, Refinery Intermediate Stream
Company : For: Tesoro Refining & Marketing Co.
19100 Ridgewood Parkway, San Antonio, TX 78259
Tesoro Call Center : (877) 783-7676 Chemtrec
(Emergency Contact)
: (800) 424-9300
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Regulatory status : This material is considered hazardous by the Occupational Safety and Health
Administration (OSHA) Hazard Communication Standard (29 CFR 1910.1200).
Signal Word : DANGER
Hazard Summary : Extremely flammable. Irritating to eyes and respiratory system. Affects central
nervous system. Harmful or fatal if swallowed. Aspiration Hazard.
Potential Health Effects
Eyes : High vapor concentration or contact may cause irritation and discomfort.
Skin : Brief contact may cause slight irritation. Skin irritation leading to dermatitis may
occur upon prolonged or repeated contact. Can be absorbed through skin.
Ingestion : Aspiration hazard if liquid is inhaled into lungs, particularly from vomiting after
ingestion. Aspiration may result in chemical pneumonia, severe lung damage,
respiratory failure and even death.
Inhalation : Vapors or mists from this material can irritate the nose, throat, and lungs, and
can cause signs and symptoms of central nervous system depression,
depending on the concentration and duration of exposure. Inhalation of high
concentrations may cause central nervous system depression such as dizziness,
Specific Hazard
Reactivity
Health
NFPA: Flammability
1 0
3
FLAMMABILITY
PHYSICAL
HEALTH
3
0
1
HMIS III:
0 = Insignificant, 1 = Slight, 2 = Moderate,
3 = High, 4 = ExtremeMATERIAL SAFETY DATA SHEET NAPHTHA Page 2 of 14
2 / 14
drowsiness, headache, and similar narcotic symptoms, but no long-term effects.
Chronic Exposure : Long-term exposure may cause effects to specific organs, such as to the liver,
kidneys, blood, nervous system, and skin. Contains benzene, which can cause
blood disease, including anemia and leukemia.
Target Organs : Skin, Central nervous system, Liver, Kidney, Blood
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS-No. Weight %
Naphtha; Low boiling point naphtha 8030-30-6 100%
N-hexane 110-54-3 25 – 35%
Xylene 1330-20-7 25 – 35%
Toluene 108-88-3 15 – 20%
Cyclohexane 110-82-7 15 – 20%
Pentane 109-66-0 15 – 20%
Heptane [and isomers] 142-82-5 12.5 – 15%
Ethylbenzene 100-41-4 5 – 7%
Benzene 71-43-2 3 – 5% 1,2,4-Trimethylbenzene 95-63-6 2 – 3%
Sulfur 7704-34-9 0 – 1.5%
SECTION 4. FIRST AID MEASURES
General advice : Remove from exposure, lie down. In the case of accident or if you feel unwell,
seek medical advice immediately (show the label where possible). When
symptoms persist or in all cases of doubt, seek medical advice. Never give
anything by mouth to an unconscious person. Take off all contaminated clothing
immediately and thoroughly wash material from skin.
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Seek medical attention immediately.
Skin contact : In case of contact, immediately flush skin with plenty of water. Take off
contaminated clothing and shoes immediately. Wash contaminated clothing
before re-use. Contaminated leather, particularly footwear, must be discarded.
Note that contaminated clothing may be a fire hazard. Seek medical advice if
symptoms persist or develop.
Eye contact : Remove contact lenses. In the case of contact with eyes, rinse immediately with
plenty of water and seek medical advice.
Ingestion : If swallowed Do NOT induce vomiting. Never give anything by mouth to an
unconscious person. Seek medical attention immediately. MATERIAL SAFETY DATA SHEET NAPHTHA Page 3 of 14
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Notes to physician : Symptoms: Dizziness, Discomfort, Headache, Nausea, Kidney disorders, Liver
disorders.
SECTION 5. FIRE-FIGHTING MEASURES
Form : Liquid
Flash point -typical : -21.7 °C (-7.1 °F)
Auto Ignition temperature : 225 °C (437 °F)
Lower explosive limit : 1.2 %(V)
Upper explosive limit : 6.9 % (V)
Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Do not
use a solid water stream as it may scatter and spread fire.
Specific hazards during fire
fighting
: SMALL FIRES: Any extinguisher suitable for Class B fires, dry chemical, CO2,
water spray, fire fighting foam, or Halon.
LARGE FIRES: Water spray, fog or fire fighting foam. Water may be ineffective for
fighting the fire, but may be used to cool fire-exposed containers.
Special protective equipment
for fire-fighters
: Fire fighters should wear positive pressure self-contained breathing apparatus
(SCBA) and full turnout gear. Firefighters’ protective clothing will provide limited
protection.
Further information : Isolate area around container involved in fire. Cool tanks, shells, and containers
exposed to fire and excessive heat with water. For massive fires the use of
unmanned hose holders or monitor nozzles may be advantageous to further
minimize personnel exposure. Major fires may require withdrawal, allowing the
tank to burn. Large storage tank fires typically require specially trained personnel
and equipment to extinguish the fire, often including the need for properly applied
fire fighting foam. Exposure to decomposition products may be a hazard to health.
Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment. Use water spray to cool unopened containers. Fire
residues and contaminated fire extinguishing water must be disposed of in
accordance with local regulations.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Evacuate personnel to safe areas. Ventilate the area. Remove all sources of
ignition. Response and clean-up crews must be properly trained and must utilize
proper protective equipment (see Section 8).
Environmental precautions : Should not be released into the environment. Avoid subsoil penetration. If the
product contaminates rivers and lakes or drains, inform respective authorities.
Methods for cleaning up : Contain and collect spillage with non-combustible absorbent material, (e.g. sand,
earth, diatomaceous earth, vermiculite) and place in container for disposal
according to local / national regulations.
SECTION 7. HANDLING AND STORAGE
Handling : Keep away from fire, sparks and heated surfaces. No smoking near areas where
material is stored or handled. The product should only be stored and handled in MATERIAL SAFETY DATA SHEET NAPHTHA Page 4 of 14
4 / 14
areas with intrinsically safe electrical classification.
Advice on protection against
fire and explosion
: Hydrocarbon liquids including this product can act as a non-conductive flammable
liquid (or static accumulators), and may form ignitable vapor-air mixtures in storage
tanks or other containers. Precautions to prevent static-initated fire or explosion
during transfer, storage or handling, include but are not limited to these examples:
(1) Ground and bond containers during product transfers. Grounding and
bonding may not be adequate protection to prevent ignition or explosion of
hydrocarbon liquids and vapors that are static accumulators.
(2) Special slow load procedures for “switch loading” must be followed to
avoid the static ignition hazard that can exist when higher flash point
material (such as fuel oil or diesel) is loaded into tanks previously
containing low flash point products (such gasoline or naphtha).
(3) Storage tank level floats must be effectively bonded.
For more information on precautions to prevent static-initated fire or explosion, see
NFPA 77, Recommended Practice on Static Electricity (2007), and API
Recommended Practice 2003, Protection Against Ignitions Arising Out of Static,
Lightning, and Stray Currents (2008).
Dust explosion class : Not applicable
Requirements for storage
areas and containers
: Keep away from flame, sparks, excessive temperatures and open flame. Use
approved containers. Keep containers closed and clearly labeled. Empty or
partially full product containers or vessels may contain explosive vapors. Do not
pressurize, cut, heat, weld or expose containers to sources of ignition. Store in a
well-ventilated area. The storage area should comply with NFPA 30 “Flammable
and Combustible Liquid Code”. The cleaning of tanks previously containing this
product should follow API Recommended Practice (RP) 2013 “Cleaning Mobile
Tanks In Flammable and Combustible Liquid Service” and API RP 2015 “Cleaning
Petroleum Storage Tanks”.
Advice on common storage : Keep away from food, drink and animal feed. Incompatible with oxidizing agents.
Incompatible with acids.
Other data : No decomposition if stored and applied as directed.
SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
List Components CAS-No. Type: Value
OSHA Benzene – 29 CFR 1910.1028 71-43-2 TWA 1 ppm
71-43-2 STEL 5 ppm
71-43-2 OSHA_AL 0.5 ppm
OSHA Z1 Naphtha; Low boiling point naphtha 8030-30-6 PEL 100 ppm 400 mg/m3
Xylene 1330-20-7 PEL 100 ppm 435 mg/m3
N-hexane 110-54-3 PEL 500 ppm 1,800 mg/m3
Cyclohexane 110-82-7 PEL 300 ppm 1,050 mg/m3
Heptane [and isomers] 142-82-5 PEL 500 ppm 2,000 mg/m3
Ethylbenzene 100-41-4 PEL 100 ppm 435 mg/m3
ACGIH Naphtha; Low boiling point naphtha 8030-30-6 TWA 400 ppm MATERIAL SAFETY DATA SHEET NAPHTHA Page 5 of 14
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Xylene 1330-20-7 TWA 100 ppm
1330-20-7 STEL 150 ppm
N-hexane 110-54-3 TWA 50 ppm
Toluene 108-88-3 TWA 50 ppm
Cyclohexane 110-82-7 TWA 100 ppm
Pentane 109-66-0 TWA 600 ppm
Heptane [and isomers] 142-82-5 TWA 400 ppm
142-82-5 STEL 500 ppm
Ethylbenzene 100-41-4 TWA 100 ppm
100-41-4 STEL 125 ppm
Benzene 71-43-2 TWA 0.5 ppm
71-43-2 STEL 2.5 ppm
Engineering measures : Use adequate ventilation to keep gas and vapor concentrations of this product
below occupational exposure and flammability limits, particularly in confined
spaces. Use only intrinsically safe electrical equipment approved for use in
classified areas.
Eye protection : Safety glasses or goggles are recommended where there is a possibility of
splashing or spraying. Ensure that eyewash stations and safety showers are close
to the workstation location.
Hand protection : Gloves constructed of nitrile or neoprene are recommended. Consult manufacturer
specifications for further information.
Skin and body protection : If needed to prevent skin contact, chemical protective clothing such as of DuPont
TyChem®, Saranex or equivalent recommended based on degree of exposure.
The resistance of specific material may vary from product to product as well as
with degree of exposure.
Respiratory protection : A NIOSH/ MSHA-approved air-purifying respirator with organic vapor cartridges or
canister may be permissible under certain circumstances where airborne
concentrations are or may be expected to exceed exposure limits or for odor or
irritation. Protection provided by air-purifying respirators is limited. Refer to OSHA
29 CFR 1910.134, ANSI Z88.2-1992, NIOSH Respirator Decision Logic, and the
manufacturer for additional guidance on respiratory protection selection. Use a
NIOSH/ MSHA-approved positive-pressure supplied-air respirator if there is a
potential for uncontrolled release, exposure levels are not known, in oxygendeficient atmospheres, or any other circumstance where an air-purifying respirator
may not provide adequate protection.
Work / Hygiene practices : Emergency eye wash capability should be available in the near proximity to
operations presenting a potential splash exposure. Use good personal hygiene
practices. Avoid repeated and/or prolonged skin exposure. Wash hands before
eating, drinking, smoking, or using toilet facilities. Do not use as a cleaning solvent
on the skin. Do not use solvents or harsh abrasive skin cleaners for washing this
product from exposed skin areas. Waterless hand cleaners are effective.
Promptly remove contaminated clothing and launder before reuse. Use care when
laundering to prevent the formation of flammable vapors which could ignite via
washer or dryer. Consider the need to discard contaminated leather shoes and
gloves. MATERIAL SAFETY DATA SHEET NAPHTHA Page 6 of 14
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SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid
Appearance : Colorless to light yellow
Odor : Characteristic hydrocarbon-like
Flash point – typical : -21.7 °C (-7.1 °F)
Auto Ignition temperature : 225 °C (437 °F)
Thermal decomposition : Heating can release hazardous gases, No decomposition if stored and applied as
directed.
Lower explosive limit : 1.2 % (V)
Upper explosive limit : 6.9 % (V)
pH : Not applicable
Specific gravity : 0.77 (H20=1)
Boiling point : 26.7 – 148.9 °C(80.1 – 300.0 °F)
Vapor Pressure : 758 – 896 hPa
at 20 °C (68 °F)
Vapor Density (Air = 1) : 3.5
Water solubility : Negligible
Viscosity, kinematic : Not determined
Percent Volatiles : 100 %
Work / Hygiene practices Emergency eye wash capability should be available in the near proximity to
operations presenting a potential splash exposure. Use good personal hygiene
practices. Avoid repeated and/or prolonged skin exposure. Wash hands before
eating, drinking, smoking, or using toilet facilities. Do not use as a cleaning
solvent on the skin. Do not use solvents or harsh abrasive skin cleaners for
washing this product from exposed skin areas. Waterless hand cleaners are
effective. Promptly remove contaminated clothing and launder before reuse. Use
care when laundering to prevent the formation of flammable vapors which could
ignite via washer or dryer. Consider the need to discard contaminated leather
shoes and gloves.
SECTION 10. STABILITY AND REACTIVITY
Conditions to avoid : Avoid high temperatures, open flames, sparks, welding, smoking and other
ignition sources.
Materials to avoid : Strong acids and strong bases. Oxidizing agents.
Hazardous decomposition
products
: Carbon monoxide, carbon dioxide and noncombusted hydrocarbons (smoke).
Thermal decomposition : Heating can release hazardous gases. No decomposition if stored and applied as
directed.
Hazardous reactions : Vapors may form explosive mixture with air. Hazardous polymerization does not
occur. Note: Stable under recommended storage conditions. MATERIAL SAFETY DATA SHEET NAPHTHA Page 7 of 14
7 / 14
SECTION 11. TOXICOLOGICAL INFORMATION
Carcinogenicity
NTP : Benzene (CAS-No.: 71-43-2)
IARC : Ethylbenzene (CAS-No.: 100-41-4)
Benzene (CAS-No.: 71-43-2)
OSHA : Benzene (CAS-No.: 71-43-2)
CA Prop 65 : WARNING! This product contains a chemical known to the State of California to
cause cancer.
Ethylbenzene (CAS-No.: 100-41-4)
Benzene (CAS-No.: 71-43-2)
: WARNING! This product contains a chemical known to the State of California to
cause birth defects or other reproductive harm.
Toluene (CAS-No.: 108-88-3)
Benzene (CAS-No.: 71-43-2)
Skin irritation : Repeated or prolonged contact with the preparation may cause removal of natural
fat from the skin resulting in desiccation of the skin.
The product may be absorbed through the skin.
Eye irritation : The liquid splashed in the eyes may cause irritation and reversible damage.
Strong lachrymation can make it difficult to escape
Further information : This product contains benzene. Human health studies indicate that prolonged
and/or repeated overexposure to benzene may cause damage to the blood-forming
system (particularly bone marrow), and serious blood disorders such as aplastic
anemia and leukemia. Benzene is listed as a human carcinogen by the NTP, IARC,
OSHA and ACGIH. Acute toxicity of benzene results primarily from depression of
the central nervous system (CNS). Inhalation of concentrations over 50 ppm can
produce headache, lassitude, weariness, dizziness, drowsiness, or excitation.
Exposure to very high levels can result in unconsciousness and death.
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and
vomiting.
Ingestion may cause gastrointestinal disturbances, including irritation, nausea,
vomiting and diarrhea, and central nervous (brain) effects similar to alcohol
intoxication. In severe cases, tremors, convulsions, loss of consciousness, coma,
respiratory arrest and death may occur.
Component:MATERIAL SAFETY DATA SHEET NAPHTHA Page 8 of 14
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N-hexane 110-54-3 Acute oral toxicity: LD50 rat
Dose: 25,000 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: 2,001 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 171.6 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Skin irritation
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
Teratogenicity: N11.00418960
Xylene 1330-20-7 Acute oral toxicity: LD50 rat
Dose: 2,840 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: ca. 4,500 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 6,350 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Mild skin irritation
Repeated or prolonged exposure may cause skin irritation and dermatitis, due to
degreasing properties of the product.
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
Toluene 108-88-3 Acute oral toxicity: LD50 rat
Dose: 636 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: 12,124 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 49 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Mild skin irritation
Prolonged skin contact may defat the skin and produce dermatitis.
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
Cyclohexane 110-82-7 Acute dermal toxicity: LD50 rabbit
Dose: 2,001 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 14 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Skin irritation
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
Pentane 109-66-0 Acute oral toxicity: LD50 rat
Dose: 2,001 mg/kg
Acute inhalation toxicity: LC50 rat MATERIAL SAFETY DATA SHEET NAPHTHA Page 9 of 14
9 / 14
Dose: 364 mg/l
Exposure time: 4 h
Skin irritation: Repeated or prolonged exposure may cause skin irritation and dermatitis,
due to degreasing properties of the product.
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
Heptane [and isomers] 142-82-5 Acute oral toxicity: LD50 rat
Dose: 15,001 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 103 g/m3
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Skin irritation
Repeated or prolonged exposure may cause skin irritation and dermatitis, due to
degreasing properties of the product.
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
Ethylbenzene 100-41-4 Acute oral toxicity: LD50 rat
Dose: 3,500 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: 15,500 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 18 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Mild skin irritation
Eye irritation: Classification: Irritating to eyes.
Result: Risk of serious damage to eyes.
Benzene 71-43-2 Acute oral toxicity: LD50 rat
Dose: 930 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 44 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Mild skin irritation
Repeated or prolonged exposure may cause skin irritation and dermatitis, due to
degreasing properties of the product.
Eye irritation: Classification: Irritating to eyes.
Result: Risk of serious damage to eyes.
1,2,4-Trimethylbenzene 95-63-6 Acute inhalation toxicity: LC50 rat
Dose: 18 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Skin irritation
Eye irritation: Classification: Irritating to eyes.
Result: Eye irritationMATERIAL SAFETY DATA SHEET NAPHTHA Page 10 of 14
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Sulfur 7704-34-9 Acute oral toxicity: LD50 rat
Dose: 5,001 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: 2,001 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 9.24 mg/l
Exposure time: 4 h
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
SECTION 12. ECOLOGICAL INFORMATION
Additional ecological
information
: Keep out of sewers, drainage areas, and waterways. Report spills and releases, as
applicable, under Federal and State regulations.
Component:
N-hexane 110-54-3 Toxicity to fish:
LC50
Species: Pimephales promelas (fathead minnow)
Dose: 2.5 mg/l
Exposure time: 96 h
Acute and prolonged toxicity for aquatic invertebrates:
EC50
Species: Daphnia magna (Water flea)
Dose: 2.1 mg/l
Exposure time: 48 h
Toluene 108-88-3 Toxicity to fish:
LC50
Species: Carassius auratus (goldfish)
Dose: 13 mg/l
Exposure time: 96 h
Acute and prolonged toxicity for aquatic invertebrates:
EC50
Species: Daphnia magna (Water flea)
Dose: 11.5 mg/l
Exposure time: 48 h
Toxicity to algae:
IC50
Species: Selenastrum capricornutum (green algae)
Dose: 12 mg/l
Exposure time: 72 h
Cyclohexane 110-82-7 Acute and prolonged toxicity for aquatic invertebrates:
EC50
Species: Daphnia magna (Water flea)
Dose: 3.78 mg/l
Exposure time: 48 h
Pentane 109-66-0 Acute and prolonged toxicity for aquatic invertebrates:
EC50
Species: Daphnia magna (Water flea)
Dose: 9.74 mg/l
Exposure time: 48 h
Heptane [and isomers] 142-82-5 Toxicity to fish:
LC50
Species: Carassius auratus (goldfish)
Dose: 4 mg/l
Exposure time: 24 h MATERIAL SAFETY DATA SHEET NAPHTHA Page 11 of 14
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Acute and prolonged toxicity for aquatic invertebrates:
EC50
Species: Daphnia magna (Water flea)
Dose: 1.5 mg/l
Exposure time: 48 h
1,2,4-Trimethylbenzene 95-63-6 Toxicity to fish:
LC50
Species: Pimephales promelas (fathead minnow)
Dose: 7.72 mg/l
Exposure time: 96 h
Acute and prolonged toxicity for aquatic invertebrates:
EC50
Species: Daphnia
Dose: 3.6 mg/l
Exposure time: 48 h
Sulfur 7704-34-9 Acute and prolonged toxicity for aquatic invertebrates:
EC0
Species: Daphnia magna (Water flea)
Dose: > 10,000 mg/l
Exposure time: 24 h
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal : Dispose of container and unused contents in accordance with federal, state and
local requirements.
SECTION 14. TRANSPORT INFORMATION
CFR
Proper shipping name : PETROLEUM DISTILLATES, N.O.S.
UN-No. : 1268
Class : 3
Packing group : II
Hazard inducer : (Naphtha; Low boiling point naphtha)
TDG
Proper shipping name : PETROLEUM DISTILLATES, N.O.S.
UN-No. : UN1268
Class : 3
Packing group : II
Hazard inducer : (Naphtha; Low boiling point naphtha)
IATA Cargo Transport
UN UN-No. : UN1268
Description of the goods : PETROLEUM DISTILLATES, N.O.S.
(Naphtha; Low boiling point naphtha)
Class : 3
Packaging group : II
ICAO-Labels : 3
Packing instruction (cargo
aircraft)
: 364
Packing instruction (cargo
aircraft)
: Y341 MATERIAL SAFETY DATA SHEET NAPHTHA Page 12 of 14
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IATA Passenger Transport
UN UN-No. : UN1268
Description of the goods : PETROLEUM DISTILLATES, N.O.S.
(Naphtha; Low boiling point naphtha)
Class : 3
Packaging group : II
ICAO-Labels : 3
Packing instruction
(passenger aircraft)
: 353
Packing instruction
(passenger aircraft)
: Y341
IMDG-Code
UN-No. : UN 1268
Description of the goods : PETROLEUM DISTILLATES, N.O.S.
(Naphtha; Low boiling point naphtha)
Class : 3
Packaging group : II
IMDG-Labels : 3
EmS Number : F-E S-E
Marine pollutant : No
SECTION 15. REGULATORY INFORMATION
OSHA Hazards : Flammable liquid
Moderate skin irritant
Severe eye irritant
Carcinogen
Teratogen
TSCA Status : On TSCA Inventory
DSL Status : All components of this product are on the Canadian DSL list.
SARA 311/312 Hazards : Fire Hazard
Acute Health Hazard
Chronic Health Hazard
SARA III US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 313 Toxic
Chemicals (40 CFR 372.65) – Supplier Notification Required
Components CAS-No.
1,2,4-Trimethylbenzene 95-63-6
Benzene 71-43-2
Ethylbenzene 100-41-4
Cyclohexane 110-82-7
Toluene 108-88-3
N-hexane 110-54-3
Xylene 1330-20-7
PENN RTK US. Pennsylvania Worker and Community Right-to-Know Law (34 Pa. Code Chap. 301-323) MATERIAL SAFETY DATA SHEET NAPHTHA Page 13 of 14
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Components CAS-No.
Heptane [and isomers] 142-82-5
Ethylbenzene 100-41-4
Benzene 71-43-2
1,2,4-Trimethylbenzene 95-63-6
Sulfur 7704-34-9
Pentane 109-66-0
Naphtha; Low boiling point naphtha 8030-30-6
Xylene 1330-20-7
N-hexane 110-54-3
Toluene 108-88-3
Cyclohexane 110-82-7
MASS RTK US. Massachusetts Commonwealth’s Right-to-Know Law (Appendix A to 105 Code of Massachusetts Regulations
Section 670.000)
Components CAS-No.
Heptane [and isomers] 142-82-5
Ethylbenzene 100-41-4
Benzene 71-43-2
1,2,4-Trimethylbenzene 95-63-6
Sulfur 7704-34-9
Naphtha; Low boiling point naphtha 8030-30-6
Xylene 1330-20-7
N-hexane 110-54-3
Toluene 108-88-3
Cyclohexane 110-82-7
NJ RTK US. New Jersey Worker and Community Right-to-Know Act (New Jersey Statute Annotated Section 34:5A-5)
Components CAS-No.
Heptane [and isomers] 142-82-5
Ethylbenzene 100-41-4
Benzene 71-43-2
1,2,4-Trimethylbenzene 95-63-6
Sulfur 7704-34-9
Naphtha; Low boiling point naphtha 8030-30-6
Xylene 1330-20-7
N-hexane 110-54-3 MATERIAL SAFETY DATA SHEET NAPHTHA Page 14 of 14
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Toluene 108-88-3
Cyclohexane 110-82-7
CERCLA SECTION 103 and SARA SECTION 304 (RELEASE
TO THE ENVIROMENT)
The CERCLA definition of hazardous substances contains a
“petroleum exclusion” clause which exempts crude oil. Fractions of
crude oil, and products (both finished and intermediate) from the
crude oil refining process and any indigenous components of such
from the CERCLA Section 103 reporting requirements. However,
other federal reporting requirements, including SARA Section 304,
as well as the Clean Water Act may still apply.
California Prop. 65 : WARNING! This product contains a chemical known to the State of California to
cause cancer.
Ethylbenzene 100-41-4
Benzene 71-43-2
WARNING! This product contains a chemical known to the State of California to
cause birth defects or other reproductive harm.
Toluene 108-88-3
Benzene 71-43-2
SECTION 16. OTHER INFORMATION
Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text.
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Revision Date : 01/27/2011
79, 80, 81, 83, 165, 264, 318, 1017, 1018, 1019, 1020, 1021, 1027, 1032, 1055, 1136, 1716
http://biotech.law.lsu.edu/blaw/dodd/corres/pdf/60505h_0189/60505h.pdf
DEPARTMENT OF DEFENSE
HAZARDOUS CHEMICAL
WARNING LABELING SYSTEM
OFFICE OF THE
ASSISTANT SECRETARY OF DEFENSE
(FORCE MANAGEMENT AND PERSONNEL)
JUNE 1989.
.
June 1989
Department of Defense Hazardous Chemical Warning
Labeling System
.
FOREWORD
,.,
This Handbook is issued under the authority of, and in accordance with, DoD Instruction 6050.5, ‘Hazardous Material Information System, ” January 25, 1978. This Handbook, the “Department of Defense Hazardous Chemical Warning Labeling System, establishes a standard label format and uniform labeling system throughout DoD for identifying hazardous materials used by DoD personnel.
In addition, this publication provides an additional training resource to help DoD comply with the training and worker information requirements of the Occupational Safety and Health Administration’ s Hazard Communication Standard (29 C. F. Il. 1910.1200) .
This publication applies to the Office of the Secretary of Defense, the Military Departments, the Joint Staff, the unified
and Specified Commandsr and the Defense Agencies. It is effective immediately.
Forward recommended changes to this Handbook through appropriate
channels to:
Director, Safety and Occupational Health Policy
OASD (FM&P), ODASD (FSE&S)
RCIOITI 3A272, The Pentagon Washington, D.C. 20301-4000
DoD Components may obtain copies of this Handbook through their
own publications channels. Other Federal Agencies and the public
may obtain copies from the U.S. Department of Commerce, National
4 Technical Information Service, 5285 Port Royal Road, Springfield,
Excerpt from GUIDE 128 [Flammable Liquids (Non-Polar / Water-Immiscible)]:HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. Substance may be transported hot. If molten aluminum is involved, refer to GUIDE 169. (ERG, 2008)
Inhalation of concentrated vapor may cause intoxication. Liquid is not very irritating to skin or eyes but may get into lungs by aspiration. (USCG, 1999)
Reactivity Profile
PETROLEUM NAPHTHA, [FLAMMABLE LIQUID LABEL] may be incompatible with strong oxidizing agents like nitric acid. Charring may occur followed by ignition of unreacted material and other nearby combustibles. In other settings, mostly unreactive. Not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents. When heated sufficiently or when ignited in the presence of air, oxygen or strong oxidizing agents, burns exothermically to produce mostly carbon dioxide and water.
Fire Extinguishing Agents Not to Be Used: Water may be ineffective.Fire Extinguishing Agents: Foam, carbon dioxide, or dry chemical (USCG, 1999)
Non-Fire Response
Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. (AAR, 2003)
Skin: Wear appropriate personal protective clothing to prevent skin contact.Eyes: Wear appropriate eye protection to prevent eye contact.Wash skin: The worker should immediately wash the skin when it becomes contaminated.Remove: Work clothing that becomes wet or significantly contaminated should be removed and replaced.Change: No recommendation is made specifying the need for the worker to change clothing after the work shift. (NIOSH, 2003)
Eye: If this chemical contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately. Contact lenses should not be worn when working with this chemical.Skin: If this chemical contacts the skin, promptly wash the contaminated skin with soap and water. If this chemical penetrates the clothing promptly remove the clothing and wash the skin with soap and water. Get medical attention promptly.Breathing: If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. If breathing has stopped, perform mouth-to-mouth resuscitation. Keep the affected person warm and at rest. Get medical attention as soon as possible.Swallow: If this chemical has been swallowed, get medical attention immediately. (NIOSH, 1997)
did you know that naptha is the key component in pavement sealer?
read all about it from the Federal Aviation Administration. now why would you put this stuff in your medicine?
Here is Dukes file of what I have done so far as to treatment and some updated pictures of Dukes shoulder with the THC oil applied.
I will send you weekly updates.
I was thinking about how Duke is the first to take this sort of treatment and he is sort of a Pioneer to this treatment. I was wondering if you had any Veterinarians in your area that you might be able to contact to see if they had any current patients that the doctor is treating for cancer or not treating for cancer. Some people once their told their dog has cancer they simply let the dog live out their final days at home and they when the dog is in too much pain or can’t get up anymore that’s when the Dr. or Vet put them to sleep. Maybe the Dr. might be willing to let you have the name of one or two patients and you can approach them and offer them a treatment program if they agree to be fully documented as to what happens.
Be aware that the Dr. may not want to participate or be involved or just say no. Use tact and diplomacy to get him to give you the names of a few of his patients currently going through cancer with their pets.
I think if there is two cases going on (Duke and you) then we can compare notes and progress.
It’s just a thought, the more documentation we can present with pictures and video the better we are of having it accepted as a treatment for dogs or cats and eventually people.
Keep sending Duke your prayers,
Cody
Most recent pictures of Duke the Cancer Fighting Dog
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Author’s note*****
Duke’s dad would like everyone to know that if you have multiple dogs, you need to watch the dog being treated for signs that the other dogs are sensing some weakness in your pooch and picking on them for it. Duke lives with a lot of other dogs. We have spoken about methods so that Duke is more alert so he can have more positive interactions with his canine buddies. We have suggested that Duke get most of his internal oil at night time when his pals are more likely to want to lie down and sleep beside him rather than pick on him in play because his consciousness is altered.
________________________________
June 30, 2012
Here is an update on Duke the dog, his owner writes “I am looking more closely at Dukes lump and it seems to feel different. What I mean is, when I would feel his lump before using the THC was hard and seemed attachd to his muscles or meat or bone.
Today for the first time it feels almost like it’s breaking loose from the bone or muscle and becoming looser and moveable. Example, put a baseball under a towel and tighten down the towel to where its hard to roll the ball around. Now loosen up the towel just a bit and notice how the ball seems easier to roll around.
What’s going on?” I replied to him that as long as he keeps the dogs body saturated in THC, then the tumor will devour itself, this process is called “Autophagy”
For those of you that have been to H.E.A.R. (Happy Endings Animal Rescue) know who Duke is.
He is a Greyhound mix that greets
people when they come by to visit our rescue.
Duke is about 10 years old and over the last few
Months has developed a lump in his left shoulder which is now the size of a Mellon.
I have taken him
him to two of our Vets and both have said that I should just go ahead and put him down and end his suffering.
About 2 weeks ago I read a story about Tommy Chong from Cheech and Chong comedy team and found out
that Tommy Chong has Prostate Cancer and instead of treating it the normal way through chemo and surgery
that he is going to treat it with THC Hemp Oil (also known as: cannibals or marijuana oil). The THC in this plant
is known to cure Cancer.
I contacted the people at Phoenix Tears and explained who we are and all about Duke
I even sent pictures of the tumor and how it’s growing in his shoulder. The person I spoke with (Ronnie Smith)
have provided me with enough Hemp Oil to cure Duke of his Cancer. I am very excited to start treatment which will
take about 3 weeks to complete and hopefully at the end, Duke will be cured of his Cancer and will live a long and happy
Life.
Check back often for updates on his progress as I plan do document the entire treatment.
Cancer in dogs is responsible
for over 60% of the deaths of dogs that die.
Those that get cancer, most of their owners can’t afford the treatment which
could run from $5,000 to $10,000 and gives NO guarantees.
With this documented case on Duke I am hoping to shed a light on
alternate treatment for cancer in dogs and hopefully more people will go this holistic treatment and save more lives.
I have already been given the death sentence from 2 Veterinarians about Duke, so I really don’t have nothing to loose by at
least trying the treatment with the THC OIL. I will take plenty of pictures as to his progress and post them on this website.
WISH DUKE LUCK AND KEEP YOUR EMAILS OF HOPE COMING IN
Treatment is scheduled to start on Monday June 25, 2012
Check back for updates and please keep your donations coming in.
HELP H.E.A.R. GO GREEN WITH YOUR DONATION
As many of you know we are running this Rescue totally off the Grid for over a Year now.
We currently have a few solar panels, some batteries and a generator that helps to run this place.
We could do so much more if we had more solar panels and finished building our water harvesting system.
We are seeking a private individual or Company who can help us finish these projects in the form of a
Grant or Gift. All Donations are Tax Deductible and it could really make life here for the dogs more enjoyable.
Where a Dog – Get’s to be a Dog
Being in a Shelter doesn’t have to mean being in a cage 24/7.
A Temporary Home, Until Their New Forever Home is Found.
HOW WOULD YOU FEEL IF EVERYONE YOU KNEW OR LOVED, LEFT YOU…
“Where would we go if H.E.A.R. should ever close”?
This would be the end of the road for most of us…
Some of us are too old
Some of us have health issues
Some of us have temperament problems from being abused
Some of us are breeds that people are afraid of and
Some of us are the wrong color. (Black Dogs)
H.E.A.R. IS OUR FOREVER HOMEWe are Registered with the State of Tennessee & IRS
To Receive Charitable Donations – EIN# 26-1353836.
Over the Years, we have Received Donations from all across America, Canada, Europe and even Australia.
Aye, yah! everybody was gettin in my face fighting, i explain my points as fast as lightning…. in fact I can be a little bit frightening… But I type with expert timing.
They were funky Canna men from funky Cannatown
hey were Marking them buds up and they were chopping them grows down
It’s an ancient Medicinal art and everybody knew their part
From a seed into a smoke, and toking from the bowl
everybody was gettin in my face fighting, i explain my points as fast as lightning…. in fact I can be a little bit frightening… But I type with expert timing.
There was wayward walkin Billy and big Tommy Chong
He said here comes the big boss, lets get it on
We took a bow and made a stand, started swinging with the hand
The sudden motion made me skip now we’re into a brand knew trip
everybody was gettin in my face fighting, i explain my points as fast as lightning…. in fact I can be a little bit frightening… But I type with expert timing.
everybody was gettin in my face fighting, i explain my points as fast as lightning…. in fact I can be a little bit frightening… But I type with expert timing.
I want to say a few things about who Fat Freddy is and how he came to life as a human for all who don’t know about it. In the form of a comic book, Fat Freddy is a name that Gilbert Shelton created from his own mind in 1969. The comic book stories were conceived and written by Gilbert and others. I will now try to explain the truth about what has happened over the last 30 years.
Gilbert Shelton went to college at The Univ. of Texas and had some good friends there. Three of them were to become the basis for his comic book. There was Joe Brown and the real Fat Freddy, they were into getting high while they went to school. Joe Brown told this story to me before his death in 1988. While in school Joe brown met a man his name was Mable (Ralph Moore) he was a dope smuggler from Memphis Tenn. from 1954. I can say his name now because he to has passed away.
In 1954 Ralph took his family on vacation to Ft. Lauderdale Fla. He was a taxi cab driver in Memphis and when people would ask for him to take them to a whorehouse, he would take them to Mables. In doing so he got the name of Mable. In Ft. Lauderdale he met some bikers from California who told him about the starting trade in Marijuana smuggling from Mexico. He was interested in this so he went home and sold his house, cab and all he could, quit his job, got a divorce and went to Mexico to build his trade.
He worked at this until 1967/68 and then retired from it, in doing so he picked up a hitchhiker by the name of Joe Brown. Who then with his other friends in Austin became his friends. Mable moved into Austin and got to know Gilbert, Joe, and Fat Freddy well. In being a dope smuggler he was wealthy, so when graduation came for them Mable called them together and told them that he wanted to give each one a gift.
Joe Brown said he wanted to have a head shop, so Ralph bought a house and they named it Oat Willies. Joe said he owned it for three years and then sold it as he stayed to stoned, to keep it running. It has since become the largest one around.
Gilbert Shelton said he wanted to start a comic book so Ralph bought him The Rip off Press and gave it to him. He then started the Fabulous Furry Freak Brothers and others. They were named: Freewheeling Franklin (Joe Brown), Phineas (Gilberts imagination), and Fat Freddy (Unknown). These became comics of the early 1970’s.
The original Fat Freddy told Ralph that he had had enough and wanted nothing but his name never to be mentioned again. Ralph said OK to him. They then went there own ways Joe owned Oat Willies and after he sold it became a taxi cab driver in Austin where he was when I met him. Gilbert started The Rip off Press and was in California. Fat Freddy disappeared.
Now it gets to me, I knew nothing about the story above in 1976 when I met Ralph Moore and became his friend. I was working for Southwestern Bell at the time and due to a divorce I got into reading The Furry Freak Brothers (I like the Cat.). They had a concert in Austin that gave me the idea to put one on called The Furry Freak Brothers First Annual Freak Party Convention. I started to put it together in March 1976. Booking bands for October 1976. I was going to go on stage as Fat Freddy using Cheech & Chong as MCs. I talked to Cheech to book them.
I set up the bands and got an attorney to handle it, so it was set up as well as it could be. In telling my attorney that I was to go on stage as Fat Freddy, she said that he was copyrighted and I could not unless I got permission to from Gilbert Shelton. So I called The Rip Off press 8 Times in one day to get it from Gilbert, but he was always out of the office or not available. In other words, he was putting me off this pissed me off.
So in going home that night I went by my friends house (Ralph Moore) and in going in he said: “ You are mad about something, what is bothering you?” I said: “I’ve called Gilbert Shelton 8 times and he won’t talk to me about Fat Freddy. He keeps putting me off.” Ralph then said: “You want to talk to Gilbert? Then he then reached over and picked up his phone and dialed the # from his memory and said “This is Ralph I want to talk to Gilbert. Gilbert a friend of mine wants to talk to you.” He then gave me the phone. I talked to Gilbert and he gave me my copyright protection so I then became Fat Freddy to go on stage as him. Ralph asked me if I would be home later I said I would.
About an hour later he called me and asked if I would come over to his house. I went over and there was Ralph and a longhaired blond headed man with him. Ralph then said “I want to introduce you to the real Freewheeling Franklin, his name is Joe Brown.” They then gave me a comic book and told me that of all the stories that Gilbert wrote only one was true and it was in that book. It was about when Joe met Ralph and was only two pages long. In reading it I will have to say it was just like them in real life. Right down to the point where Ralph said he didn’t smoke Grass. I talked him into smoking a joint with me and Joe one time and was told by Joe that was the only joint he had ever smoked with him since they met.
I knew these two men and had the opportunity to learn a lot about there life of the past. I spent many a long hour with them both in conversation about how they lived. Mable was killed in Memphis in 1979 and was buried in Austin Texas. I, like Joe Brown have never been to his grave. We feel that the law is still video taping it.
I was hurt in a motorcycle accident in Oct. 1988 the same year that Joe Brown passed away. So now there is only Gilbert and I still alive in this world. I have no idea what is going to happen with this story now. The Rip Off Press has gone out of business and that leaves me free to put out a Fat Freddy comic book that is a true story of my life minus the CAT of whom I liked a lot. I hope some day that Gilbert will bring it back into my life – who knows.
Note from Breezy…. Fat Freddy now lives in Colorado. He is the proud holder of a Medicinal Cannabis License commonly known as a “Red Card”. He continues his activism fight. He has been using Phoenix Tears Oil to treat his diabetes (both internally and skin symptoms of the disease topically) please visit the documentation of this amazing healing beginning here
Please also see the recent blog post about meeting Fat Freddy in person written by writer and #Occupy Together protester Steve Bass here
Over the Years, we have Received Donations from all across
Kiefair.com DIY cannabis and more 