If you are looking for a safe medication, look no further than what the hemp plant can provide. On top of all that it’s a medicine we can all grow and produce ourselves. Also there is no need for a doctor’s supervision with its use.
When the hemp plant is grown for medicinal use, you now have your own medical system that is much safer and effective than anything our current medical system provides. You still may require a doctor to set your broken leg, but you will no longer need the chemicals they have been pushing upon us.
Hemp is medicine for the masses and no one has the right to control its use. We are all different and we all have different tolerances for practically everything. So it is up to each and every one of us to determine for ourselves how much oil we require to maintain good health.
Over the years people have come to me who after years of treatment by the medical system did not even have a diagnosis for their conditions. But the oil exercised its amazing healing power and their medical problems were solved.
Another aspect of the use of hemp as medicine is its anti-aging properties. As we age, our vital organs deteriorate and of course this impairs the function of these organs.
Hemp oil rejuvenates vital organs even in small doses it is very common for people to report to me that they feel 20 to 30 years younger after only ingesting the oil for a short time.
Now let’s take it to the next level. What about people who ingest larger quantities of oil over a longer period of time like myself? After 9 years on the oil my body does not appear to be that of a 60 year old man. Instead, my body has the appearance of someone who is a great deal younger. When I have the oil at my disposal I like to take about a quarter of a gram a day. Of course, due to short supply, quite often I must go without so my own treatment has been erratic to say the least.
From my own experience with the oil I cannot help but wonder what would happen if a person was to ingest larger quantities of oil over a longer period of time. If a person were to do this, can they actually reverse the aging process and grow younger instead of aging.
From the oils effect on my own body by all appearances this seems to be the case. Someday soon when I have enough oil I intend to start taking a gram a day for a year to see what effect it has on my body.
Many people who have taken the oil have stated that they thought it to be the fountain of youth. From my own experiences with the oil I believe this to be true.
*****Author’s note… the above information is my research source. It is how I learned about Phoenix Tears and why I wanted to try them… ^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^
*****THE BELOW information is data gathered based on personal observation. I have utmost respect for Mr. Rick Simpson and his work, but I in no way have his permission or endorsement… just for honesty and clarity.
Fat Freddy has had a sore on his back for about 3 years and it would not heal! We started putting Rick Simpson Oil on it on November 23, then the next day we checked it and then checked it every 3 days afterwards, changing the oil and bandage every 3 days as well! Here is the progress so far! (WARNING THIS IS GRAPHIC!)
On December 9, 2011 this is how the wound looked….
12/09/11 7:12pm progress on Fat Freddy’s shoulder… WOW!
*note* our supply of Phoenix Tears AKA Rick Simpson Oil AKA Hash oil ran out during the course of therapy. We substituted one treatment for Hemp-EaZe™ THERAPY CREAM. We have also been using the Hemp-EaZe™ for Baby & Me Spray to wipe away any excess oil when we change the bandage. Hemp-EaZe™ THERAPY CREAM is available here: http://tierrasolfarm.com/Hemp-EaZe-THERAPY-CREAM-333.htm Hemp-EaZe™ for Baby & Me Spray is available here: http://tierrasolfarm.com/Hemp-EaZe-for-Baby-Me-Spray-335.htm
In the future, I plan to do a blog post about my personal experience with the phoenix tears for my fibromyalgia and chronic fatigue syndrome. I doubt I will have any fantastic images, but I have already seen improvement since I have been ingesting this therapy.
Fat Freddy‘s treatment began on November 23, 2011. We changed his bandage (covered with phoenix tears oil) every 3 days until around December 12, 2011.
Here is the progress from ! December 12, 2011 to December 26. 2011 (WARNING THIS IS GRAPHIC!)
We saw amazing progress. When the scab initially fell off in November, it left a pitted area from where the sore had been for so many years. In addition to healing over, this ugly pit began to fill in with pretty pink, healthy skin.
We began changing the bandage every 6 days as the healing proceeded.
I did some additional research on diabetes and it’s effects on the skin.
According to WebMD, “Every 30 seconds, somewhere in the world, someone loses a lower limb as a result of diabetes”……
In my opinion, nearly all of those amputations could be prevented if we would stop running from the cure for so many diseases & start using Rick Simpson‘s Run From The Cure method to make Hemp oil.
For more info on “Fat Freddy” of the Freak Brother’s Comics (a longtime cannabis freedom fighter and the dude whose back we are healing) please visit: http://www.fatfreddy.com/
to buy Hemp EaZe Baby & Me Spray (the non thc lotion I have been using along with the PTO) please visit:
Around one edge, some light scaling of skin remains. The scar itself continues to fill in where it had been an sunken area on the back. We are continuing to change the bandage about once a week. Have a blessed day. We will continue to update this post as we can. The authoress of the post is currently nursing a broken pelvis.
We changed the bandage this morning, lo and behold, all the scaling has gone! We are now continuing treatment only as scar reduction! It has been so amazing to watch this horrible wound heal up and begin to disappear. Here are the latest pics.
There seemed to have been a deeper infection going on. We continued therapy for scar reductive therapy. Now we have entered a second phase of deeper healing. We’re calling it the “Dave Triplett effect”
Cured: A Cannabis Story (A Film By David Triplett)
Cannabis cured my skin cancer. This is my story.
It has been proven that concentrated cannabis extract oil cures cancer.
Why hasn’t The U.S. National Cancer Institute or The American Cancer Society tested Cannabis Oil?. Is it lack of personnel (2,100 USNCI staff members) or limited financial support (USNCI 2010 budget of $5.1 Billion dollars!)
Cannabis Concentrate or extract is the same as Rick Simpson’s “Hemp Oil”. Hemp seed oil is NOT what Rick Simpson is making and using.
Google “cannabinoids” and “cancer”.
Google “endocannabinoids” and “cancer”
Google “THC” and “Cancer”.
Google pubmed, go there and look up “endocannabinoids” and “cancer”, as well as “cannabinoids” and “cancer”.
Google Dr. Robert Dr Robert Melamede and cancer”.
May 18, 2011 still images…. We left Fat Fred’s back open to the air for nearly 1 week prior to these images. This gave his skin some time to breathe without a bandage and demonstrates how quickly the phoenix tears therapy treats wounds and also how quickly a wound suffers when therapy is removed.
Washing and Debridement (http://en.wikipedia.org/wiki/Debridement) of Fat Freddy’s Back. Then we cover it with a bandage covered in Phoenix Tears Oil (hash oil, hemp oil, concentrated cannabis oil)
musical selection composed by: Tchaikovsky
“Nutcracker Suite” “March”
Continuing the healing with phoenix tears therapy on Fat Freddy’s back. We suspect the sore to be a diabetic ulcer and/or skin cancer. Fat Freddy does not like doctors, so a “proper diagnosis” is impossible. There is already a lively debate in the comments on youtube for this video. I will be altering my method slightly to prove a point because of the complaints registered there.
We show what 11 days without the Phoenix tears therapy does and discuss the Naphtha video a little more. Fat Freddy has a few words to say to you as well.
October 29, 2012 UPDATE and FINAL WORDS ON THIS POST:
I must admit that I have not updated you all on this story in FAR too long. I must also admit that all I was truly able to do for this ulcer is to prevent it from becoming overly dangerous to a very resistive patient. I could have achieved more success had I been able to convince Fat Freddy to stop wearing his suspenders. I believe that the wound began as a pressure sore from those suspenders, and as long as he continues to wear them, he will continue to have a sore there. During my prolonged illness this summer, I had someone else take over his wound care for a time. They did not follow instructions or treat his wound and within a few weeks, his shoulder looked like the “before” images in this post. When therapy resumed, his wound resumed the healing process and was back to the level of healing it had been when I last provided documentation. I have a few videos and images that have been piling up on this story, however due to the patient’s stubbornness, I have little faith that this wound will ever truly heal. What can be done is continuing the therapy and preventing a major infection in a geriatric body.
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2. Love is Stronger than Justice (The Munificent Seven)
3. Fields of Gold
4. Heavy Cloud No Rain
5. She’s Too Good For me
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A phenotype (from Greek phainein, ‘to show’ + typos, ‘type’) is the
composite of an organism‘s observable characteristics or traits: such
as its morphology, development, biochemical or physiological
properties, phenology, behavior, and products of behavior (such as a
bird’s nest). Phenotypes result from the expression of an organism’s
genes as well as the influence of environmental factors and the
interactions between the two.
The genotype of an organism is the inherited instructions it carries
within its genetic code. Not all organisms with the same genotype look
or act the same way because appearance and behavior are modified by
environmental and developmental conditions. Likewise, not all
organisms that look alike necessarily have the same genotype.
Facebook status message of Breezy Mental Ginsberg Kiefair
July 13 via mobile
Just in case I need the info later, I’m told I had 6-8 seizures last night.
Treating with extra white widow. Should have a fresh batch of tears ready for tasting soon.
Perhaps since ingestion levels dropped, the once a week widow was no longer enough.
Last seizure was about 3 months prior with the weekly bowl of white widow.
As of July 18, 2012 no further seizure activity was seen with an increase
of white widow dosage and re-introduction of phoenix tears therapy.
A friend of mine was donated some phoenix tears oil from an understandably unnamed source. She could not take it to a lab for testing and was afraid to use it. She put a sample into my hands. So, on Monday I tested it. I have a high tolerance and was in a lot of pain, so I took a larger than a grain of rice dab. From the moment it touched my tongue, it burned. It was naphtha! I knew it, but it was far too late. Soon, My nervous system was soon on fire. Then the crazy symptoms came. I got to a point of pain and insanity that was torture for myself and all around me. The crazy lasted for days… the pain is still there. If you have mental health issues on any level, avoid naphtha extracted products like the plague! Its not worth it. It causes cancer too.
naphtha is so toxic, the Department of Defense (DoD) uses is as a template for how they classify “dangerous” chemicals…. you’re using naphtha to make your Rick Simpson – Phoenix Tears therapy? your’re inviting so much attention from the government it is stupid. They track each and every purchase of that substance btw.
Material Safety Data Sheet
Naphtha
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : Naphtha
Synonyms : Light Naphtha, Japan Open Spec Bonded Naphtha, SNG Naphtha, Light Cat
Naphtha, Sweet Virgin Naphtha (SVN), Debutanized Naphtha, Atmospheric
Naphtha (DAN), HCU Light Naphtha, Light CR Gasoline, Full Range Cracked
Naphtha, Full Range Hydrocracked Naphtha, Full Range Reformed Naphtha,
Light Chemical Treated Naphtha, Light Cracked Naphtha, Light Hydrocracked
Naphtha, Light Hydrotreated Naphtha, Aviation Alkylate Naphtha, 888100004450
MSDS Number : 888100004450 Version : 2.12
Product Use Description : Fuel Component, Refinery Intermediate Stream
Company : For: Tesoro Refining & Marketing Co.
19100 Ridgewood Parkway, San Antonio, TX 78259
Tesoro Call Center : (877) 783-7676 Chemtrec
(Emergency Contact)
: (800) 424-9300
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Regulatory status : This material is considered hazardous by the Occupational Safety and Health
Administration (OSHA) Hazard Communication Standard (29 CFR 1910.1200).
Signal Word : DANGER
Hazard Summary : Extremely flammable. Irritating to eyes and respiratory system. Affects central
nervous system. Harmful or fatal if swallowed. Aspiration Hazard.
Potential Health Effects
Eyes : High vapor concentration or contact may cause irritation and discomfort.
Skin : Brief contact may cause slight irritation. Skin irritation leading to dermatitis may
occur upon prolonged or repeated contact. Can be absorbed through skin.
Ingestion : Aspiration hazard if liquid is inhaled into lungs, particularly from vomiting after
ingestion. Aspiration may result in chemical pneumonia, severe lung damage,
respiratory failure and even death.
Inhalation : Vapors or mists from this material can irritate the nose, throat, and lungs, and
can cause signs and symptoms of central nervous system depression,
depending on the concentration and duration of exposure. Inhalation of high
concentrations may cause central nervous system depression such as dizziness,
Specific Hazard
Reactivity
Health
NFPA: Flammability
1 0
3
FLAMMABILITY
PHYSICAL
HEALTH
3
0
1
HMIS III:
0 = Insignificant, 1 = Slight, 2 = Moderate,
3 = High, 4 = ExtremeMATERIAL SAFETY DATA SHEET NAPHTHA Page 2 of 14
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drowsiness, headache, and similar narcotic symptoms, but no long-term effects.
Chronic Exposure : Long-term exposure may cause effects to specific organs, such as to the liver,
kidneys, blood, nervous system, and skin. Contains benzene, which can cause
blood disease, including anemia and leukemia.
Target Organs : Skin, Central nervous system, Liver, Kidney, Blood
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS-No. Weight %
Naphtha; Low boiling point naphtha 8030-30-6 100%
N-hexane 110-54-3 25 – 35%
Xylene 1330-20-7 25 – 35%
Toluene 108-88-3 15 – 20%
Cyclohexane 110-82-7 15 – 20%
Pentane 109-66-0 15 – 20%
Heptane [and isomers] 142-82-5 12.5 – 15%
Ethylbenzene 100-41-4 5 – 7%
Benzene 71-43-2 3 – 5% 1,2,4-Trimethylbenzene 95-63-6 2 – 3%
Sulfur 7704-34-9 0 – 1.5%
SECTION 4. FIRST AID MEASURES
General advice : Remove from exposure, lie down. In the case of accident or if you feel unwell,
seek medical advice immediately (show the label where possible). When
symptoms persist or in all cases of doubt, seek medical advice. Never give
anything by mouth to an unconscious person. Take off all contaminated clothing
immediately and thoroughly wash material from skin.
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Seek medical attention immediately.
Skin contact : In case of contact, immediately flush skin with plenty of water. Take off
contaminated clothing and shoes immediately. Wash contaminated clothing
before re-use. Contaminated leather, particularly footwear, must be discarded.
Note that contaminated clothing may be a fire hazard. Seek medical advice if
symptoms persist or develop.
Eye contact : Remove contact lenses. In the case of contact with eyes, rinse immediately with
plenty of water and seek medical advice.
Ingestion : If swallowed Do NOT induce vomiting. Never give anything by mouth to an
unconscious person. Seek medical attention immediately. MATERIAL SAFETY DATA SHEET NAPHTHA Page 3 of 14
3 / 14
Notes to physician : Symptoms: Dizziness, Discomfort, Headache, Nausea, Kidney disorders, Liver
disorders.
SECTION 5. FIRE-FIGHTING MEASURES
Form : Liquid
Flash point -typical : -21.7 °C (-7.1 °F)
Auto Ignition temperature : 225 °C (437 °F)
Lower explosive limit : 1.2 %(V)
Upper explosive limit : 6.9 % (V)
Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Do not
use a solid water stream as it may scatter and spread fire.
Specific hazards during fire
fighting
: SMALL FIRES: Any extinguisher suitable for Class B fires, dry chemical, CO2,
water spray, fire fighting foam, or Halon.
LARGE FIRES: Water spray, fog or fire fighting foam. Water may be ineffective for
fighting the fire, but may be used to cool fire-exposed containers.
Special protective equipment
for fire-fighters
: Fire fighters should wear positive pressure self-contained breathing apparatus
(SCBA) and full turnout gear. Firefighters’ protective clothing will provide limited
protection.
Further information : Isolate area around container involved in fire. Cool tanks, shells, and containers
exposed to fire and excessive heat with water. For massive fires the use of
unmanned hose holders or monitor nozzles may be advantageous to further
minimize personnel exposure. Major fires may require withdrawal, allowing the
tank to burn. Large storage tank fires typically require specially trained personnel
and equipment to extinguish the fire, often including the need for properly applied
fire fighting foam. Exposure to decomposition products may be a hazard to health.
Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment. Use water spray to cool unopened containers. Fire
residues and contaminated fire extinguishing water must be disposed of in
accordance with local regulations.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Evacuate personnel to safe areas. Ventilate the area. Remove all sources of
ignition. Response and clean-up crews must be properly trained and must utilize
proper protective equipment (see Section 8).
Environmental precautions : Should not be released into the environment. Avoid subsoil penetration. If the
product contaminates rivers and lakes or drains, inform respective authorities.
Methods for cleaning up : Contain and collect spillage with non-combustible absorbent material, (e.g. sand,
earth, diatomaceous earth, vermiculite) and place in container for disposal
according to local / national regulations.
SECTION 7. HANDLING AND STORAGE
Handling : Keep away from fire, sparks and heated surfaces. No smoking near areas where
material is stored or handled. The product should only be stored and handled in MATERIAL SAFETY DATA SHEET NAPHTHA Page 4 of 14
4 / 14
areas with intrinsically safe electrical classification.
Advice on protection against
fire and explosion
: Hydrocarbon liquids including this product can act as a non-conductive flammable
liquid (or static accumulators), and may form ignitable vapor-air mixtures in storage
tanks or other containers. Precautions to prevent static-initated fire or explosion
during transfer, storage or handling, include but are not limited to these examples:
(1) Ground and bond containers during product transfers. Grounding and
bonding may not be adequate protection to prevent ignition or explosion of
hydrocarbon liquids and vapors that are static accumulators.
(2) Special slow load procedures for “switch loading” must be followed to
avoid the static ignition hazard that can exist when higher flash point
material (such as fuel oil or diesel) is loaded into tanks previously
containing low flash point products (such gasoline or naphtha).
(3) Storage tank level floats must be effectively bonded.
For more information on precautions to prevent static-initated fire or explosion, see
NFPA 77, Recommended Practice on Static Electricity (2007), and API
Recommended Practice 2003, Protection Against Ignitions Arising Out of Static,
Lightning, and Stray Currents (2008).
Dust explosion class : Not applicable
Requirements for storage
areas and containers
: Keep away from flame, sparks, excessive temperatures and open flame. Use
approved containers. Keep containers closed and clearly labeled. Empty or
partially full product containers or vessels may contain explosive vapors. Do not
pressurize, cut, heat, weld or expose containers to sources of ignition. Store in a
well-ventilated area. The storage area should comply with NFPA 30 “Flammable
and Combustible Liquid Code”. The cleaning of tanks previously containing this
product should follow API Recommended Practice (RP) 2013 “Cleaning Mobile
Tanks In Flammable and Combustible Liquid Service” and API RP 2015 “Cleaning
Petroleum Storage Tanks”.
Advice on common storage : Keep away from food, drink and animal feed. Incompatible with oxidizing agents.
Incompatible with acids.
Other data : No decomposition if stored and applied as directed.
SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
List Components CAS-No. Type: Value
OSHA Benzene – 29 CFR 1910.1028 71-43-2 TWA 1 ppm
71-43-2 STEL 5 ppm
71-43-2 OSHA_AL 0.5 ppm
OSHA Z1 Naphtha; Low boiling point naphtha 8030-30-6 PEL 100 ppm 400 mg/m3
Xylene 1330-20-7 PEL 100 ppm 435 mg/m3
N-hexane 110-54-3 PEL 500 ppm 1,800 mg/m3
Cyclohexane 110-82-7 PEL 300 ppm 1,050 mg/m3
Heptane [and isomers] 142-82-5 PEL 500 ppm 2,000 mg/m3
Ethylbenzene 100-41-4 PEL 100 ppm 435 mg/m3
ACGIH Naphtha; Low boiling point naphtha 8030-30-6 TWA 400 ppm MATERIAL SAFETY DATA SHEET NAPHTHA Page 5 of 14
5 / 14
Xylene 1330-20-7 TWA 100 ppm
1330-20-7 STEL 150 ppm
N-hexane 110-54-3 TWA 50 ppm
Toluene 108-88-3 TWA 50 ppm
Cyclohexane 110-82-7 TWA 100 ppm
Pentane 109-66-0 TWA 600 ppm
Heptane [and isomers] 142-82-5 TWA 400 ppm
142-82-5 STEL 500 ppm
Ethylbenzene 100-41-4 TWA 100 ppm
100-41-4 STEL 125 ppm
Benzene 71-43-2 TWA 0.5 ppm
71-43-2 STEL 2.5 ppm
Engineering measures : Use adequate ventilation to keep gas and vapor concentrations of this product
below occupational exposure and flammability limits, particularly in confined
spaces. Use only intrinsically safe electrical equipment approved for use in
classified areas.
Eye protection : Safety glasses or goggles are recommended where there is a possibility of
splashing or spraying. Ensure that eyewash stations and safety showers are close
to the workstation location.
Hand protection : Gloves constructed of nitrile or neoprene are recommended. Consult manufacturer
specifications for further information.
Skin and body protection : If needed to prevent skin contact, chemical protective clothing such as of DuPont
TyChem®, Saranex or equivalent recommended based on degree of exposure.
The resistance of specific material may vary from product to product as well as
with degree of exposure.
Respiratory protection : A NIOSH/ MSHA-approved air-purifying respirator with organic vapor cartridges or
canister may be permissible under certain circumstances where airborne
concentrations are or may be expected to exceed exposure limits or for odor or
irritation. Protection provided by air-purifying respirators is limited. Refer to OSHA
29 CFR 1910.134, ANSI Z88.2-1992, NIOSH Respirator Decision Logic, and the
manufacturer for additional guidance on respiratory protection selection. Use a
NIOSH/ MSHA-approved positive-pressure supplied-air respirator if there is a
potential for uncontrolled release, exposure levels are not known, in oxygendeficient atmospheres, or any other circumstance where an air-purifying respirator
may not provide adequate protection.
Work / Hygiene practices : Emergency eye wash capability should be available in the near proximity to
operations presenting a potential splash exposure. Use good personal hygiene
practices. Avoid repeated and/or prolonged skin exposure. Wash hands before
eating, drinking, smoking, or using toilet facilities. Do not use as a cleaning solvent
on the skin. Do not use solvents or harsh abrasive skin cleaners for washing this
product from exposed skin areas. Waterless hand cleaners are effective.
Promptly remove contaminated clothing and launder before reuse. Use care when
laundering to prevent the formation of flammable vapors which could ignite via
washer or dryer. Consider the need to discard contaminated leather shoes and
gloves. MATERIAL SAFETY DATA SHEET NAPHTHA Page 6 of 14
6 / 14
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid
Appearance : Colorless to light yellow
Odor : Characteristic hydrocarbon-like
Flash point – typical : -21.7 °C (-7.1 °F)
Auto Ignition temperature : 225 °C (437 °F)
Thermal decomposition : Heating can release hazardous gases, No decomposition if stored and applied as
directed.
Lower explosive limit : 1.2 % (V)
Upper explosive limit : 6.9 % (V)
pH : Not applicable
Specific gravity : 0.77 (H20=1)
Boiling point : 26.7 – 148.9 °C(80.1 – 300.0 °F)
Vapor Pressure : 758 – 896 hPa
at 20 °C (68 °F)
Vapor Density (Air = 1) : 3.5
Water solubility : Negligible
Viscosity, kinematic : Not determined
Percent Volatiles : 100 %
Work / Hygiene practices Emergency eye wash capability should be available in the near proximity to
operations presenting a potential splash exposure. Use good personal hygiene
practices. Avoid repeated and/or prolonged skin exposure. Wash hands before
eating, drinking, smoking, or using toilet facilities. Do not use as a cleaning
solvent on the skin. Do not use solvents or harsh abrasive skin cleaners for
washing this product from exposed skin areas. Waterless hand cleaners are
effective. Promptly remove contaminated clothing and launder before reuse. Use
care when laundering to prevent the formation of flammable vapors which could
ignite via washer or dryer. Consider the need to discard contaminated leather
shoes and gloves.
SECTION 10. STABILITY AND REACTIVITY
Conditions to avoid : Avoid high temperatures, open flames, sparks, welding, smoking and other
ignition sources.
Materials to avoid : Strong acids and strong bases. Oxidizing agents.
Hazardous decomposition
products
: Carbon monoxide, carbon dioxide and noncombusted hydrocarbons (smoke).
Thermal decomposition : Heating can release hazardous gases. No decomposition if stored and applied as
directed.
Hazardous reactions : Vapors may form explosive mixture with air. Hazardous polymerization does not
occur. Note: Stable under recommended storage conditions. MATERIAL SAFETY DATA SHEET NAPHTHA Page 7 of 14
7 / 14
SECTION 11. TOXICOLOGICAL INFORMATION
Carcinogenicity
NTP : Benzene (CAS-No.: 71-43-2)
IARC : Ethylbenzene (CAS-No.: 100-41-4)
Benzene (CAS-No.: 71-43-2)
OSHA : Benzene (CAS-No.: 71-43-2)
CA Prop 65 : WARNING! This product contains a chemical known to the State of California to
cause cancer.
Ethylbenzene (CAS-No.: 100-41-4)
Benzene (CAS-No.: 71-43-2)
: WARNING! This product contains a chemical known to the State of California to
cause birth defects or other reproductive harm.
Toluene (CAS-No.: 108-88-3)
Benzene (CAS-No.: 71-43-2)
Skin irritation : Repeated or prolonged contact with the preparation may cause removal of natural
fat from the skin resulting in desiccation of the skin.
The product may be absorbed through the skin.
Eye irritation : The liquid splashed in the eyes may cause irritation and reversible damage.
Strong lachrymation can make it difficult to escape
Further information : This product contains benzene. Human health studies indicate that prolonged
and/or repeated overexposure to benzene may cause damage to the blood-forming
system (particularly bone marrow), and serious blood disorders such as aplastic
anemia and leukemia. Benzene is listed as a human carcinogen by the NTP, IARC,
OSHA and ACGIH. Acute toxicity of benzene results primarily from depression of
the central nervous system (CNS). Inhalation of concentrations over 50 ppm can
produce headache, lassitude, weariness, dizziness, drowsiness, or excitation.
Exposure to very high levels can result in unconsciousness and death.
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and
vomiting.
Ingestion may cause gastrointestinal disturbances, including irritation, nausea,
vomiting and diarrhea, and central nervous (brain) effects similar to alcohol
intoxication. In severe cases, tremors, convulsions, loss of consciousness, coma,
respiratory arrest and death may occur.
Component:MATERIAL SAFETY DATA SHEET NAPHTHA Page 8 of 14
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N-hexane 110-54-3 Acute oral toxicity: LD50 rat
Dose: 25,000 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: 2,001 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 171.6 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Skin irritation
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
Teratogenicity: N11.00418960
Xylene 1330-20-7 Acute oral toxicity: LD50 rat
Dose: 2,840 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: ca. 4,500 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 6,350 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Mild skin irritation
Repeated or prolonged exposure may cause skin irritation and dermatitis, due to
degreasing properties of the product.
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
Toluene 108-88-3 Acute oral toxicity: LD50 rat
Dose: 636 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: 12,124 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 49 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Mild skin irritation
Prolonged skin contact may defat the skin and produce dermatitis.
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
Cyclohexane 110-82-7 Acute dermal toxicity: LD50 rabbit
Dose: 2,001 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 14 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Skin irritation
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
Pentane 109-66-0 Acute oral toxicity: LD50 rat
Dose: 2,001 mg/kg
Acute inhalation toxicity: LC50 rat MATERIAL SAFETY DATA SHEET NAPHTHA Page 9 of 14
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Dose: 364 mg/l
Exposure time: 4 h
Skin irritation: Repeated or prolonged exposure may cause skin irritation and dermatitis,
due to degreasing properties of the product.
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
Heptane [and isomers] 142-82-5 Acute oral toxicity: LD50 rat
Dose: 15,001 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 103 g/m3
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Skin irritation
Repeated or prolonged exposure may cause skin irritation and dermatitis, due to
degreasing properties of the product.
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
Ethylbenzene 100-41-4 Acute oral toxicity: LD50 rat
Dose: 3,500 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: 15,500 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 18 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Mild skin irritation
Eye irritation: Classification: Irritating to eyes.
Result: Risk of serious damage to eyes.
Benzene 71-43-2 Acute oral toxicity: LD50 rat
Dose: 930 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 44 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Mild skin irritation
Repeated or prolonged exposure may cause skin irritation and dermatitis, due to
degreasing properties of the product.
Eye irritation: Classification: Irritating to eyes.
Result: Risk of serious damage to eyes.
1,2,4-Trimethylbenzene 95-63-6 Acute inhalation toxicity: LC50 rat
Dose: 18 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Skin irritation
Eye irritation: Classification: Irritating to eyes.
Result: Eye irritationMATERIAL SAFETY DATA SHEET NAPHTHA Page 10 of 14
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Sulfur 7704-34-9 Acute oral toxicity: LD50 rat
Dose: 5,001 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: 2,001 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 9.24 mg/l
Exposure time: 4 h
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
SECTION 12. ECOLOGICAL INFORMATION
Additional ecological
information
: Keep out of sewers, drainage areas, and waterways. Report spills and releases, as
applicable, under Federal and State regulations.
Component:
N-hexane 110-54-3 Toxicity to fish:
LC50
Species: Pimephales promelas (fathead minnow)
Dose: 2.5 mg/l
Exposure time: 96 h
Acute and prolonged toxicity for aquatic invertebrates:
EC50
Species: Daphnia magna (Water flea)
Dose: 2.1 mg/l
Exposure time: 48 h
Toluene 108-88-3 Toxicity to fish:
LC50
Species: Carassius auratus (goldfish)
Dose: 13 mg/l
Exposure time: 96 h
Acute and prolonged toxicity for aquatic invertebrates:
EC50
Species: Daphnia magna (Water flea)
Dose: 11.5 mg/l
Exposure time: 48 h
Toxicity to algae:
IC50
Species: Selenastrum capricornutum (green algae)
Dose: 12 mg/l
Exposure time: 72 h
Cyclohexane 110-82-7 Acute and prolonged toxicity for aquatic invertebrates:
EC50
Species: Daphnia magna (Water flea)
Dose: 3.78 mg/l
Exposure time: 48 h
Pentane 109-66-0 Acute and prolonged toxicity for aquatic invertebrates:
EC50
Species: Daphnia magna (Water flea)
Dose: 9.74 mg/l
Exposure time: 48 h
Heptane [and isomers] 142-82-5 Toxicity to fish:
LC50
Species: Carassius auratus (goldfish)
Dose: 4 mg/l
Exposure time: 24 h MATERIAL SAFETY DATA SHEET NAPHTHA Page 11 of 14
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Acute and prolonged toxicity for aquatic invertebrates:
EC50
Species: Daphnia magna (Water flea)
Dose: 1.5 mg/l
Exposure time: 48 h
1,2,4-Trimethylbenzene 95-63-6 Toxicity to fish:
LC50
Species: Pimephales promelas (fathead minnow)
Dose: 7.72 mg/l
Exposure time: 96 h
Acute and prolonged toxicity for aquatic invertebrates:
EC50
Species: Daphnia
Dose: 3.6 mg/l
Exposure time: 48 h
Sulfur 7704-34-9 Acute and prolonged toxicity for aquatic invertebrates:
EC0
Species: Daphnia magna (Water flea)
Dose: > 10,000 mg/l
Exposure time: 24 h
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal : Dispose of container and unused contents in accordance with federal, state and
local requirements.
SECTION 14. TRANSPORT INFORMATION
CFR
Proper shipping name : PETROLEUM DISTILLATES, N.O.S.
UN-No. : 1268
Class : 3
Packing group : II
Hazard inducer : (Naphtha; Low boiling point naphtha)
TDG
Proper shipping name : PETROLEUM DISTILLATES, N.O.S.
UN-No. : UN1268
Class : 3
Packing group : II
Hazard inducer : (Naphtha; Low boiling point naphtha)
IATA Cargo Transport
UN UN-No. : UN1268
Description of the goods : PETROLEUM DISTILLATES, N.O.S.
(Naphtha; Low boiling point naphtha)
Class : 3
Packaging group : II
ICAO-Labels : 3
Packing instruction (cargo
aircraft)
: 364
Packing instruction (cargo
aircraft)
: Y341 MATERIAL SAFETY DATA SHEET NAPHTHA Page 12 of 14
12 / 14
IATA Passenger Transport
UN UN-No. : UN1268
Description of the goods : PETROLEUM DISTILLATES, N.O.S.
(Naphtha; Low boiling point naphtha)
Class : 3
Packaging group : II
ICAO-Labels : 3
Packing instruction
(passenger aircraft)
: 353
Packing instruction
(passenger aircraft)
: Y341
IMDG-Code
UN-No. : UN 1268
Description of the goods : PETROLEUM DISTILLATES, N.O.S.
(Naphtha; Low boiling point naphtha)
Class : 3
Packaging group : II
IMDG-Labels : 3
EmS Number : F-E S-E
Marine pollutant : No
SECTION 15. REGULATORY INFORMATION
OSHA Hazards : Flammable liquid
Moderate skin irritant
Severe eye irritant
Carcinogen
Teratogen
TSCA Status : On TSCA Inventory
DSL Status : All components of this product are on the Canadian DSL list.
SARA 311/312 Hazards : Fire Hazard
Acute Health Hazard
Chronic Health Hazard
SARA III US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 313 Toxic
Chemicals (40 CFR 372.65) – Supplier Notification Required
Components CAS-No.
1,2,4-Trimethylbenzene 95-63-6
Benzene 71-43-2
Ethylbenzene 100-41-4
Cyclohexane 110-82-7
Toluene 108-88-3
N-hexane 110-54-3
Xylene 1330-20-7
PENN RTK US. Pennsylvania Worker and Community Right-to-Know Law (34 Pa. Code Chap. 301-323) MATERIAL SAFETY DATA SHEET NAPHTHA Page 13 of 14
13 / 14
Components CAS-No.
Heptane [and isomers] 142-82-5
Ethylbenzene 100-41-4
Benzene 71-43-2
1,2,4-Trimethylbenzene 95-63-6
Sulfur 7704-34-9
Pentane 109-66-0
Naphtha; Low boiling point naphtha 8030-30-6
Xylene 1330-20-7
N-hexane 110-54-3
Toluene 108-88-3
Cyclohexane 110-82-7
MASS RTK US. Massachusetts Commonwealth’s Right-to-Know Law (Appendix A to 105 Code of Massachusetts Regulations
Section 670.000)
Components CAS-No.
Heptane [and isomers] 142-82-5
Ethylbenzene 100-41-4
Benzene 71-43-2
1,2,4-Trimethylbenzene 95-63-6
Sulfur 7704-34-9
Naphtha; Low boiling point naphtha 8030-30-6
Xylene 1330-20-7
N-hexane 110-54-3
Toluene 108-88-3
Cyclohexane 110-82-7
NJ RTK US. New Jersey Worker and Community Right-to-Know Act (New Jersey Statute Annotated Section 34:5A-5)
Components CAS-No.
Heptane [and isomers] 142-82-5
Ethylbenzene 100-41-4
Benzene 71-43-2
1,2,4-Trimethylbenzene 95-63-6
Sulfur 7704-34-9
Naphtha; Low boiling point naphtha 8030-30-6
Xylene 1330-20-7
N-hexane 110-54-3 MATERIAL SAFETY DATA SHEET NAPHTHA Page 14 of 14
14 / 14
Toluene 108-88-3
Cyclohexane 110-82-7
CERCLA SECTION 103 and SARA SECTION 304 (RELEASE
TO THE ENVIROMENT)
The CERCLA definition of hazardous substances contains a
“petroleum exclusion” clause which exempts crude oil. Fractions of
crude oil, and products (both finished and intermediate) from the
crude oil refining process and any indigenous components of such
from the CERCLA Section 103 reporting requirements. However,
other federal reporting requirements, including SARA Section 304,
as well as the Clean Water Act may still apply.
California Prop. 65 : WARNING! This product contains a chemical known to the State of California to
cause cancer.
Ethylbenzene 100-41-4
Benzene 71-43-2
WARNING! This product contains a chemical known to the State of California to
cause birth defects or other reproductive harm.
Toluene 108-88-3
Benzene 71-43-2
SECTION 16. OTHER INFORMATION
Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text.
Template
Prepared by
: GWU mbH
Birlenbacher Str. 18
D-57078 Siegen
Germany
Telephone: +49-(0)271-88072-0
Revision Date : 01/27/2011
79, 80, 81, 83, 165, 264, 318, 1017, 1018, 1019, 1020, 1021, 1027, 1032, 1055, 1136, 1716
http://biotech.law.lsu.edu/blaw/dodd/corres/pdf/60505h_0189/60505h.pdf
DEPARTMENT OF DEFENSE
HAZARDOUS CHEMICAL
WARNING LABELING SYSTEM
OFFICE OF THE
ASSISTANT SECRETARY OF DEFENSE
(FORCE MANAGEMENT AND PERSONNEL)
JUNE 1989.
.
June 1989
Department of Defense Hazardous Chemical Warning
Labeling System
.
FOREWORD
,.,
This Handbook is issued under the authority of, and in accordance with, DoD Instruction 6050.5, ‘Hazardous Material Information System, ” January 25, 1978. This Handbook, the “Department of Defense Hazardous Chemical Warning Labeling System, establishes a standard label format and uniform labeling system throughout DoD for identifying hazardous materials used by DoD personnel.
In addition, this publication provides an additional training resource to help DoD comply with the training and worker information requirements of the Occupational Safety and Health Administration’ s Hazard Communication Standard (29 C. F. Il. 1910.1200) .
This publication applies to the Office of the Secretary of Defense, the Military Departments, the Joint Staff, the unified
and Specified Commandsr and the Defense Agencies. It is effective immediately.
Forward recommended changes to this Handbook through appropriate
channels to:
Director, Safety and Occupational Health Policy
OASD (FM&P), ODASD (FSE&S)
RCIOITI 3A272, The Pentagon Washington, D.C. 20301-4000
DoD Components may obtain copies of this Handbook through their
own publications channels. Other Federal Agencies and the public
may obtain copies from the U.S. Department of Commerce, National
4 Technical Information Service, 5285 Port Royal Road, Springfield,
Excerpt from GUIDE 128 [Flammable Liquids (Non-Polar / Water-Immiscible)]:HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. Substance may be transported hot. If molten aluminum is involved, refer to GUIDE 169. (ERG, 2008)
Inhalation of concentrated vapor may cause intoxication. Liquid is not very irritating to skin or eyes but may get into lungs by aspiration. (USCG, 1999)
Reactivity Profile
PETROLEUM NAPHTHA, [FLAMMABLE LIQUID LABEL] may be incompatible with strong oxidizing agents like nitric acid. Charring may occur followed by ignition of unreacted material and other nearby combustibles. In other settings, mostly unreactive. Not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents. When heated sufficiently or when ignited in the presence of air, oxygen or strong oxidizing agents, burns exothermically to produce mostly carbon dioxide and water.
Fire Extinguishing Agents Not to Be Used: Water may be ineffective.Fire Extinguishing Agents: Foam, carbon dioxide, or dry chemical (USCG, 1999)
Non-Fire Response
Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. (AAR, 2003)
Skin: Wear appropriate personal protective clothing to prevent skin contact.Eyes: Wear appropriate eye protection to prevent eye contact.Wash skin: The worker should immediately wash the skin when it becomes contaminated.Remove: Work clothing that becomes wet or significantly contaminated should be removed and replaced.Change: No recommendation is made specifying the need for the worker to change clothing after the work shift. (NIOSH, 2003)
Eye: If this chemical contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately. Contact lenses should not be worn when working with this chemical.Skin: If this chemical contacts the skin, promptly wash the contaminated skin with soap and water. If this chemical penetrates the clothing promptly remove the clothing and wash the skin with soap and water. Get medical attention promptly.Breathing: If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. If breathing has stopped, perform mouth-to-mouth resuscitation. Keep the affected person warm and at rest. Get medical attention as soon as possible.Swallow: If this chemical has been swallowed, get medical attention immediately. (NIOSH, 1997)
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